产品名称

英文名称：(R)-(+)-2-Diphenylphosphino-2'-methoxy-1,1'-binaphthyl

同义词

145964-33-6、134484-36-9、(S)-(2'-Methoxy-[1,1'-binaphthalen]-2-yl)diphenylphosphine、(R)-MOP、(r)-(+)-2-(diphenylphosphino)-2'-methoxy-1,1'-binaphthyl、145964-36-9、(R)-(2'-Methoxy-[1,1'-binaphthalen]-2-yl)diphenylphosphine、[1-(2-methoxynaphthalen-1-yl)naphtha、R-(+)-1,1'-联萘-2'-甲氧基-2-二苯膦

产品性质

CAS编号：145964-33-6

分子式：C33H25OP

分子量：468.54

MDL号：MFCD00269686

PubChem编号：4190002

别名：R-(+)-1,1'-联萘-2'-甲氧基-2-二苯膦

英文别名：145964-33-6|134484-36-9|(S)-(2'-Methoxy-[1,1'-binaphthalen]-2-yl)diphenylphosphine|(R)-MOP|(r)-(+)-2-(diphenylphosphino)-2'-methoxy-1,1'-binaphthyl|145964-36-9|(R)-(2'-Methoxy-[1,1'-binaphthalen]-2-yl)diphenylphosphine|[1-(2-methoxynaphthalen-1-yl)naphtha

规格或纯度：98%

英文名称：(R)-(+)-2-Diphenylphosphino-2'-methoxy-1,1'-binaphthyl

储存温度：充氩

运输条件：常规运输

产品介绍：Ligand used in palladium-catalyzed asymmetric hydrosilylation of olefins, palladium-catalyzed reduction of allylic esters, rhodium-catalyzed asymmetric addition reactions, and asymmetric amination reactions catalyzed by copper(I) complexes.(R)-MOP is used as a catalyst in the preparation of chiral tetrahydrobenzofuranone alkylideneboronates and oxindoles. Also used as a catalyst in the total synthesis of Oseltamivir Phosphate；an orally active inhibitor of influenza virus neuraminidase and an antiviral drug.

IUPAC Name：[1-(2-methoxynaphthalen-1-yl)naphthalen-2-yl]-diphenylphosphane

INCHI：InChI=1S/C33H25OP/c1-34-30-22-20-24-12-8-10-18-28(24)32(30)33-29-19-11-9-13-25(29)21-23-31(33)35(26-14-4-2-5-15-26)27-16-6-3-7-17-27/h2-23H,1H3

InChi Key：KRWTWSSMURUMDE-UHFFFAOYSA-N

Canonical SMILES：COC1=C(C2=CC=CC=C2C=C1)C3=C(C=CC4=CC=CC=C43)P(C5=CC=CC=C5)C6=CC=CC=C6

Isomeric SMILES：COC1=C(C2=CC=CC=C2C=C1)C3=C(C=CC4=CC=CC=C43)P(C5=CC=CC=C5)C6=CC=CC=C6

WGK Germany：3

PubChem CID：4190002

Reaxy-Rn：4889178

溶解性：Soluble in toluene

敏感性：对空气和湿度敏感

比旋光度：94° (C=0.3,CHCl3)

熔点：193°C

象形图：

信号词：Warning

危险声明：H315 Causes skin irritationH319 Causes serious eye irritationH335 May cause respiratory irritation

预防措施声明：P261,P305+P351+P338,P280,P302+P352,P321,P405,P501,P264,P271,P304+P340,P403+P233,P362+P364,P264+P265,P337+P317,P332+P317,P319

个人防护装备：Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter

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