产品名称

英文名称：Palladium acetate

同义词

Palladium (II) acetate、SR-01000389719、EU-0040175、BCP05504、Palladium(II) acetate、palladium-(II) acetate、UNII-0LTG3460Y5、Bis(acetato)palladium、Acetic Acid Palladium(II) Salt、AMY1789、AC-677、Diacetatopalladium、Acetic acid palladium salt、EINECS 222-164-4、Aceti、乙酸钯

产品性质

CAS编号：3375-31-3

分子式：C4H6O4Pd

分子量：224.51

Beilstein号：6086766

EC号：222-164-4

MDL号：MFCD00012453

PubChem编号：167845

别名：乙酸钯

英文别名：Palladium (II) acetate|SR-01000389719|EU-0040175|BCP05504|Palladium(II) acetate|palladium-(II) acetate|UNII-0LTG3460Y5|Bis(acetato)palladium|Acetic Acid Palladium(II) Salt|AMY1789|AC-677|Diacetatopalladium|Acetic acid palladium salt|EINECS 222-164-4|Aceti

规格或纯度：AR,Pd 46.0 - 48.0 %

英文名称：Palladium acetate

法律信息：Product of Umicore

运输条件：常规运输

产品介绍：Product classM-O, Homogeneous Catalysts, Acetate LigandsReaction typeCross Coupling Reactions with Arenes, CH-Activation, Carbonylation, Mizoroki Heck Coupling Reaction, Sonogashira-Hagihara Coupling Reaction, Suzuki-Miyaura Coupling Reaction, OxidationChemical propertiesChemical formulaC12H18O12Pd3Empirical formula[Pd(OAc)2]3Molecular weight673.53MetalPdTheoretical metal content47Physical statepowderColorred brownApplications & referencesSynthesis of 2-(4-{2-[(2R)-2-Cyclopentyl-5-(5,7-dimethyl-[1,2,4]triazolo[1,5-a]pyrimidin-2-ylmethyl)-4-hydroxy-6-oxo-3,6-dihydro-2H-pyran-2-yl]-ethyl}-2-fluoro-phenyl)-2-methyl-propionitrile on multikilogram scale using a merging Heck coupling reaction. Compound is an inhibitor of the hepatitis C viral polymerase (HCVP) enzyme.Reference Org. Proc. Res. Dev. 2006, 10, 814. (DOI 10.1021/op0600761)Reductive carbonylation of aryl halides as an alternative and mild route for the introduction of aldehyde functionality, which is mostly desired for fine chemical and pharmaceutical intermediates to open up the wide range of further possible transformations.Reference Org. Proc. Res. Dev. 2007, 11, 39. (DOI 10.1021/op060193w)Synthesis of the pyrazolopyridinone-based p38 mitogen-activated protein kinase inhibitor including a Suzuki coupling reaction. p38 MAP kinases are intercellular serine/threonine kinases which certainly regulate the production and action of several pro-inflammatory mediators. They are also involved in disease states such as rheumatoid arthritis, Crohn’s diseases and psoriasis.Reference Org. Proc. Res. Dev. 2011, 15, 31. (DOI 10.1021/op100205s)Efficient hydroformylation of aryl triflates.Reference Synthesis 1996, 470 (DOI 10.1055/s-1996-4246)Deacetylation-Diazotation-Heck-Sequence Carbon-Carbon bond formation with acetanilides as formal leaving groupsReference Adv. Synth. Catal. 2013, 355, 463 (DOI 10.1002/adsc.201200929)Deacetylation-Diazotation-Suzuki-Sequence Carbon-Carbon bond formation with acetanilides as formal leaving groups.Reference Adv. Synth. Catal. 2013, 355, 463 (DOI 10.1002/adsc.201200929)Deacetylation-Diazotation-[2+2+1]-CycloadditionReference Adv. Synth. Catal. 2013, 355, 463 (DOI 10.1002/adsc.201200929)

IUPAC Name：palladium(2+);diacetate

INCHI：InChI=1S/2C2H4O2.Pd/c2*1-2(3)4;/h2*1H3,(H,3,4);/q;;+2/p-2

InChi Key：YJVFFLUZDVXJQI-UHFFFAOYSA-L

Canonical SMILES：CC(=O)[O-].CC(=O)[O-].[Pd+2]

Isomeric SMILES：CC(=O)[O-].CC(=O)[O-].[Pd+2]

WGK Germany：3

RTECS：AJ1900000

PubChem CID：167845

UN Number：3077

Packing Group：III

溶解性：可溶于丙酮

密度：0.984

熔点：216.3-223.7°C

象形图：

信号词：Danger

危险声明：H302 Harmful if swallowedH318 Causes serious eye damageH317 May cause an allergic skin reactionH400 Very toxic to aquatic lifeH410 Very toxic to aquatic life with long lasting effects

预防措施声明：P261,P273,P280,P302+P352,P321,P501,P264,P270,P272,P333+P313,P362+P364,P391,P330,P264+P265,P301+P317,P305+P354+P338,P317

Class：9

Merck Index：6991

个人防护装备：dust mask type N95 (US),Eyeshields,Gloves

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