产品名称

英文名称：(3-Phenyl-1H-inden-1-ylidene)bis(tricyclohexylphosphine)ruthenium(II) Dichloride

同义词

250220-36-1、(3-Phenyl-1H-inden-1-ylidene)bis(tricyclohexylphosphine)ruthenium(II)dichloride、dichloro-(3-phenylinden-1-ylidene)ruthenium;tricyclohexylphosphane、(3-Phenyl-1H-inden-1-ylidene)bis(tricyclohexylphosphine)ruthenium(IV) Dichloride、(SP-5-31)-Dichl、Grubbs 催化剂 M101、双(三环己基磷)-3-苯基-1H-茚二氯化钌

产品性质

CAS编号：250220-36-1

分子式：C51H76Cl2P2Ru

分子量：923.09

MDL号：MFCD07369034

PubChem编号：11029366

别名：Grubbs 催化剂 M101|双(三环己基磷)-3-苯基-1H-茚二氯化钌|

英文别名：250220-36-1|(3-Phenyl-1H-inden-1-ylidene)bis(tricyclohexylphosphine)ruthenium(II)dichloride|dichloro-(3-phenylinden-1-ylidene)ruthenium;tricyclohexylphosphane|(3-Phenyl-1H-inden-1-ylidene)bis(tricyclohexylphosphine)ruthenium(IV) Dichloride|(SP-5-31)-Dichl

规格或纯度：≥97.0%(T)

英文名称：(3-Phenyl-1H-inden-1-ylidene)bis(tricyclohexylphosphine)ruthenium(II) Dichloride

储存温度：2-8°C储存,充氩

运输条件：冰袋运输

产品介绍：Product classM-P, Homogeneous Catalysts, Grubbs Catalyst® 1st Generation, Phosphorus Ligands - AchiralReaction typeAlkene Metathesis, Cross Metathesis, Enyne Metathesis, Ring Closing Metathesis, Self MetathesisChemical propertiesChemical formulaC51H76Cl2P2RuEmpirical formulaRu(PCy3)2(Ind)Cl2Molecular weight923.08MetalRuTheoretical metal content11Physical statepowderColorbrownApplications & referencesTotal synthesis of macrocyclic HCV protease inhibitor with RCM as key step.Reference US2009 0163706Metathesis key step in the synthesis of cyclic tripyrole pigment nonylprodigiosin.Reference J. Org. Chem. 1999, 64, 8275 (DOI 10.1021/jo991021i)Total synthesis of macrocyclic compounds which are useful as inhibitors of hepatitis C virus N33 protease.Reference US2007 0027071Macrocyclization step by ring closing metathesis in the synthesis of turrianes.Reference Chem. Eur. J. 2002, 8, 1856 (10.1002/1521-3765(20020415)88<1856AID-CHEM1856>3.0.CO;2-RView)Ring closing metathesis. Reference Chem. Comm. 2008, 2726 (DOI 10.1039/B718287B)Enyne cycloisomerization. Reference Chem. Comm. 2008, 2726 (DOI 10.1039/B718287B)Nucleophilic addition of acids to alkynes.Reference Chem. Comm. 2008, 2726 (DOI 10.1039/B718287B)Diastereoselective double ring closing metathesis.Reference Chem. Comm. 2008, 2726 (DOI 10.1039/B718287B)

IUPAC Name：dichloro-(3-phenylinden-1-ylidene)ruthenium;tricyclohexylphosphane

INCHI：InChI=1S/2C18H33P.C15H10.2ClH.Ru/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2-6-12(7-3-1)15-11-10-13-8-4-5-9-14(13)15;;;/h2*16-18H,1-15H2;1-9,11H;2*1H;/q;;;;;+2/p-2

InChi Key：UZAFZWUWHHFWOK-UHFFFAOYSA-L

Canonical SMILES：C1CCC(CC1)P(C2CCCCC2)C3CCCCC3.C1CCC(CC1)P(C2CCCCC2)C3CCCCC3.C1=CC=C(C=C1)C2=CC(=[Ru](Cl)Cl)C3=CC=CC=C32

Isomeric SMILES：C1CCC(CC1)P(C2CCCCC2)C3CCCCC3.C1CCC(CC1)P(C2CCCCC2)C3CCCCC3.C1=CC=C(C=C1)C2=CC(=[Ru](Cl)Cl)C3=CC=CC=C32

WGK Germany：3

PubChem CID：11029366

UN Number：1325

Reaxy-Rn：17903370

敏感性：对湿度，空气，热和光线敏感

熔点：120-141 °C

象形图：

信号词：Warning

危险声明：H315 Causes skin irritationH319 Causes serious eye irritation

预防措施声明：P305+P351+P338,P280,P302+P352,P321,P264,P362+P364,P264+P265,P337+P317,P332+P317

产品包装