产品名称

英文名称：Ethyl 1,3-Dithiolane-2-carboxylate

同义词

1,3-Dithiolane-2-carboxylic acid, ethyl ester 、 ETHYL1,3-DITHIOLANE-2-CARBOXYLATE 、 2-Carboethoxydithiolane 、 UNII-ZP3BM93ES6 、 ZP3BM93ES6 、 1,3-Dithiolane-2-carboxylic Acid Ethyl Ester 、 MFCD00005411 、 EINECS、1,3-二硫戊环-2-甲酸乙酯

产品性质

CAS编号：20461-99-8

分子式：C6H10O2S2

分子量：178.26

Beilstein号：118157

MDL号：MFCD00005411

PubChem编号：88551

别名：1,3-二硫戊环-2-甲酸乙酯

英文别名：1,3-Dithiolane-2-carboxylic acid, ethyl ester | ETHYL1,3-DITHIOLANE-2-CARBOXYLATE | 2-Carboethoxydithiolane | UNII-ZP3BM93ES6 | ZP3BM93ES6 | 1,3-Dithiolane-2-carboxylic Acid Ethyl Ester | MFCD00005411 | EINECS

规格或纯度：97%

英文名称：Ethyl 1,3-Dithiolane-2-carboxylate

储存温度：2-8°C储存,避光,充氩

运输条件：冰袋运输

产品介绍：α-酮酸等价物；对烯酮的共轭加成；进行顺式选择性羟醛反应的乙酸酯大位阻等价物。Ethyl 1,3-dithiolane-2-carboxylate is an α-keto acid equivalent. It participates in the conjugate additions to enones.It is a bulky equivalent of acetate undergoing syn-selective aldol reactions.Anion derived from ethyl 1,3-dithiolane-2-carboxylate participates as nucleophile during the total synthesis of the corynanthe alkaloid dihydrocorynantheol and the formal syntheses of the indole alkaloids tacamonine, rhynchophylline and hirsutine. It also participates in the conjugate addition of enolates to phenylglycinol-derived α,β-unsaturated δ-lactams.

IUPAC Name：ethyl 1,3-dithiolane-2-carboxylate

INCHI：InChI=1S/C6H10O2S2/c1-2-8-5(7)6-9-3-4-10-6/h6H,2-4H2,1H3

InChi Key：OMCSHTHLIQOHDD-UHFFFAOYSA-N

Canonical SMILES：CCOC(=O)C1SCCS1

Isomeric SMILES：CCOC(=O)C1SCCS1

WGK Germany：3

PubChem CID：88551

Reaxy-Rn：118157

密度：1.249

敏感性：对光线敏感

折光率：1.539

闪点(℉)：235.4 °F

闪点(℃)：113 °C

沸点：85 °C/0.1 mmHg

个人防护装备：Eyeshields， Gloves

产品包装