产品名称

英文名称：(S)-(+)-4,12-Bis[di(3,5-xylyl)phosphino]-[2.2]-paracyclophane

同义词

325168-88-5、325168-89-6、(S)-(+)-4,12-Bis(di(3,5-xylyl)phosphino)-[2.2]-paracyclophane、(R)-(-)-4,12-Bis[di(3,5-xylyl)phosphino]-[2.2]-paracyclophane、(S)-(+)-4,12-Bis[di(3,5-xylyl)phosphino]-[2.2]-paracyclophane、(R)-(-)-4,12-Bis(di(3,5-xylyl)phosphino)-[2.2、(S)-5,11-双(3,5-二甲苯基膦)三环[8.2.24,7]十六-己烯

产品性质

CAS编号：325168-88-5

分子式：C48H50P2

分子量：688.86

MDL号：MFCD03840578

PubChem编号：11263179

别名：(S)-5,11-双(3,5-二甲苯基膦)三环[8.2.24,7]十六-己烯

英文别名：325168-88-5|325168-89-6|(S)-(+)-4,12-Bis(di(3,5-xylyl)phosphino)-[2.2]-paracyclophane|(R)-(-)-4,12-Bis[di(3,5-xylyl)phosphino]-[2.2]-paracyclophane|(S)-(+)-4,12-Bis[di(3,5-xylyl)phosphino]-[2.2]-paracyclophane|(R)-(-)-4,12-Bis(di(3,5-xylyl)phosphino)-[2.2

规格或纯度：97%

英文名称：(S)-(+)-4,12-Bis[di(3,5-xylyl)phosphino]-[2.2]-paracyclophane

储存温度：充氩

运输条件：常规运输

产品介绍：脱氢氨基酸、甲酯和酮的不对称氢化反应的有效配体Asymmetric hydrogenation

IUPAC Name：[11-bis(3,5-dimethylphenyl)phosphanyl-5-tricyclo[8.2.2.24,7]hexadeca-1(12),4,6,10,13,15-hexaenyl]-bis(3,5-dimethylphenyl)phosphane

INCHI：InChI=1S/C48H50P2/c1-31-17-32(2)22-43(21-31)49(44-23-33(3)18-34(4)24-44)47-29-39-9-13-41(47)15-11-40-10-14-42(16-12-39)48(30-40)50(45-25-35(5)19-36(6)26-45)46-27-37(7)20-38(8)28-46/h9-10,13-14,17-30H,11-12,15-16H2,1-8H3

InChi Key：LYHOBZAADXPPNW-UHFFFAOYSA-N

Canonical SMILES：CC1=CC(=CC(=C1)P(C2=CC(=CC(=C2)C)C)C3=C4CCC5=CC(=C(CCC(=C3)C=C4)C=C5)P(C6=CC(=CC(=C6)C)C)C7=CC(=CC(=C7)C)C)C

Isomeric SMILES：CC1=CC(=CC(=C1)P(C2=CC(=CC(=C2)C)C)C3=C4CCC5=CC(=C(CCC(=C3)C=C4)C=C5)P(C6=CC(=CC(=C6)C)C)C7=CC(=CC(=C7)C)C)C

WGK Germany：3

PubChem CID：11263179

比旋光度：+61.0°, c = 0.1 in ethanol

熔点：234-238°C

象形图：

信号词：Warning

危险声明：H315 Causes skin irritationH319 Causes serious eye irritation

预防措施声明：P305+P351+P338,P280,P302+P352,P321,P264,P362+P364,P264+P265,P337+P317,P332+P317

个人防护装备：dust mask type N95 (US), Eyeshields, Gloves

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