产品名称

英文名称：(4,4'-Di-tert-butyl-2,2'-bipyridine)bis[(2-pyridinyl)phenyl]iridium(III) Hexafluorophosphate

同义词

676525-77-2、[Ir(dtbbpy)(ppy)2][PF6]、4-tert-butyl-2-(4-tert-butylpyridin-2-yl)pyridine;iridium(3+);2-phenylpyridine;hexafluorophosphate、A922981、(4,4'-Di-t-butyl-2,2'-bipyridine)bis[2-(2-pyridinyl-kN)phenyl-kC]iridium(III) hexafluorophosphate

产品性质

CAS编号：676525-77-2

分子式：C40H40F6IrN4P

分子量：913.95

PubChem编号：60146995

英文别名：676525-77-2|[Ir(dtbbpy)(ppy)2][PF6]|4-tert-butyl-2-(4-tert-butylpyridin-2-yl)pyridine;iridium(3+);2-phenylpyridine;hexafluorophosphate|A922981|(4,4'-Di-t-butyl-2,2'-bipyridine)bis[2-(2-pyridinyl-kN)phenyl-kC]iridium(III) hexafluorophosphate

规格或纯度：>85.0%(HPLC)

英文名称：(4,4'-Di-tert-butyl-2,2'-bipyridine)bis[(2-pyridinyl)phenyl]iridium(III) Hexafluorophosphate

储存温度：2-8°C储存

运输条件：冰袋运输

产品介绍：(4,4'-二叔丁基-2,2'-联吡啶)双[(2-吡啶基)苯基]铱(III)六氟磷酸盐是一种铱类光催化剂，被用于催化各种光化学反应，如• 通过氧化氮杂-亨利反应，催化 N-芳基胺与硝基烷烃的偶联。• 卤代烷烃通过原子转移自由基加成（ATRA）转化为烯烃和炔烃。• 将2-溴苯酰胺转化为相应的3,3-二取代羟吲哚。• 芳基-烷基C−C 还原型交叉偶联反应。(4,4'-Di-tert-butyl-2,2'-bipyridine)bis[(2-pyridinyl)phenyl]iridium(III) Hexafluorophosphate is an iridium-based photocatalyst which is used to drive various photochemical reactions such as• Coupling of N-arylamines and nitroalkanes via an oxidative aza-Henry reaction.• Atom transfer radical addition (ATRA) of haloalkanes to alkenes and alkynes.• Conversion of 2-bromoanilides to the corresponding 3,3-disubstituted oxindoles.• Aryl-alkyl C−C reductive cross-coupling reactions.

IUPAC Name：4-tert-butyl-2-(4-tert-butylpyridin-2-yl)pyridine;iridium(3+);2-phenylpyridine;hexafluorophosphate

INCHI：InChI=1S/C18H24N2.2C11H8N.F6P.Ir/c1-17(2,3)13-7-9-19-15(11-13)16-12-14(8-10-20-16)18(4,5)6;2*1-2-6-10(7-3-1)11-8-4-5-9-12-11;1-7(2,3,4,5)6;/h7-12H,1-6H3;2*1-6,8-9H;;/q;3*-1;+3

InChi Key：VCIVELSSYHAWGC-UHFFFAOYSA-N

Canonical SMILES：CC(C)(C)C1=CC(=NC=C1)C2=NC=CC(=C2)C(C)(C)C.C1=CC=C([C-]=C1)C2=CC=CC=N2.C1=CC=C([C-]=C1)C2=CC=CC=N2.F[P-](F)(F)(F)(F)F.[Ir+3]

Isomeric SMILES：CC(C)(C)C1=CC(=NC=C1)C2=NC=CC(=C2)C(C)(C)C.C1=CC=C([C-]=C1)C2=CC=CC=N2.C1=CC=C([C-]=C1)C2=CC=CC=N2.F[P-](F)(F)(F)(F)F.[Ir+3]

PubChem CID：60146995

Reaxy-Rn：17851176

敏感性：对光及热敏感

象形图：

信号词：Warning

危险声明：H315 Causes skin irritationH319 Causes serious eye irritationH335 May cause respiratory irritation

预防措施声明：P261,P305+P351+P338,P280,P302+P352,P321,P405,P501,P264,P271,P304+P340,P403+P233,P362+P364,P264+P265,P337+P317,P332+P317,P319

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