产品名称

英文名称：[1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium

同义词

Umicore CX93、Pd(dppf)Cl2、二氯[1,1'-双(二苯基膦)二茂铁]钯(II)

产品性质

CAS编号：72287-26-4

分子式：C34H28Cl2FeP2Pd

分子量：731.7

MDL号：MFCD00015757

别名：Umicore CX93|Pd(dppf)Cl2|二氯[1,1'-双(二苯基膦)二茂铁]钯(II)

规格或纯度：Pd 14.5%

英文名称：[1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium

储存温度：充氩

运输条件：常规运输

产品介绍：不溶于水，溶于氯仿，微溶于二氯甲烷。A catalyst for Suzuki and Stille couplingsCatalyst for C-C and C-N coupling reaction.Pd(dppf)Cl2 may be used as an effective palladium catalyst in the following reactions· Cross-coupling of sec-alkyl and n-alkyl Grignard reagents with high yield and selectivity.· Suzuki coupling of aryl boronic esters with [11C]methyl iodide to form functionalized [11C]toluene derivatives.· Kumada cross-coupling of 1,3,5-tribromobenzene with Grignard reagents to form star-shaped oligothiophenes.用途用于C-C和C-N偶联反应的催化剂。钯催化交叉偶联反应应用指南Pd(dppf)Cl2可作为一种有效的钯催化剂用于以下反应具有高产率和选择性的仲烷基和正烷基格氏试剂的交叉偶联。芳基硼酸酯与[11C]甲基碘形成官能化的[11C]甲苯衍生物的铃木偶联反应。1,3,5-三溴苯与格氏试剂形成星形低聚噻吩的Kumada交叉偶联反应。A catalyst for Suzuki and Stille couplingsCatalyst for C-C and C-N coupling reaction.Pd(dppf)Cl2 may be used as an effective palladium catalyst in the following reactions· Cross-coupling of sec-alkyl and n-alkyl Grignard reagents with high yield and selectivity.· Suzuki coupling of aryl boronic esters with [11C]methyl iodide to form functionalized [11C]toluene derivatives.· Kumada cross-coupling of 1,3,5-tribromobenzene with Grignard reagents to form star-shaped oligothiophenes.Product classM-P, Homogeneous Catalysts, Bidentate Ligands, Ferrocenyl Ligands - AchiralReaction typeCross Coupling Reactions with Arenes, Amination, Buchwald-Hartwig Aminaton, C-H Activation, Carbonylation, Negishi Coupling Reaction, Stille Reaction, Suzuki-Miyaura Coupling Reaction, OxidationChemical propertiesChemical formulaC34H28Cl2FeP2PdEmpirical formula[Pd(dppf)Cl2]Molecular weight731.71MetalPdTheoretical metal content14Physical statecrystallineColorredApplications & referencesReductive carbonylation of aryl halides as an alternative and mild route for the introduction of aldehyde functionality, which is mostly desired for fine chemical and pharmaceutical intermediates to open up the wide range of further possible transformations.Reference Org. Proc. Res. Dev. 2007, 11, 39. (DOI 10.1021/op060193w), Synthesis 1996, 470 (DOI 10.1055/s-1996-4246)High yielding Palladium catalyzed C-H arylation of electron-enriched heteroarenes with aryl bromides.Reference J. Org. Chem. 2010, 75, 6998. (DOI 10.1021/jo101433g)

WGK Germany：3

溶解性：Soluble in dichloromethane.

敏感性：对空气和湿度敏感

熔点：275-280°C

象形图：

信号词：Warning

危险声明：H315 Causes skin irritationH319 Causes serious eye irritationH335 May cause respiratory irritation

预防措施声明：P261,P305+P351+P338

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