产品名称

英文名称：Dibromobis(tri-tert-butylphosphine)dipalladium(I)

同义词

185812-86-6、PALLADIUM (I) TRI-TERT-BUTYLPHOSPHINE BROMIDE、Palladium;tritert-butylphosphane;bromide、MFCD04114019、DTXSID20747905、QMKDJYMOHBICON-UHFFFAOYSA-M、AKOS025294780、palladium(I) tri-tertbutylphosphine bromide、Palladium(I) tri-tert-butylphosphine bromi、Umicore CX71、三特丁基膦溴化钯

产品性质

CAS编号：185812-86-6

分子式：C24H54Br2P2Pd2

分子量：777.29

MDL号：MFCD04114019

PubChem编号：71317307

别名：Umicore CX71|三特丁基膦溴化钯

英文别名：185812-86-6|PALLADIUM (I) TRI-TERT-BUTYLPHOSPHINE BROMIDE|Palladium;tritert-butylphosphane;bromide|MFCD04114019|DTXSID20747905|QMKDJYMOHBICON-UHFFFAOYSA-M|AKOS025294780|palladium(I) tri-tertbutylphosphine bromide|Palladium(I) tri-tert-butylphosphine bromi

规格或纯度：98%

英文名称：Dibromobis(tri-tert-butylphosphine)dipalladium(I)

储存温度：-20°C储存,充氩

运输条件：超低温冰袋运输

产品介绍：Catalyst for C-C, C-N, and N-S bond formation.ApplicationCoupling reactions. Will activate aryl chloride and sterically hindered or electron rich aryl/vinyl bromides and iodides. Especially active in difficult aminations.Di-µ-bromobis(tri-tert-butylphosphine)dipalladium(I) is used as a catalyst for Suzuki coupling, Negishi coupling and Buchwald-hartwig amination reactions. It is used as a catalyst for C-C, C-N and C-S bond formation, gamma-arylation of alfa,beta-unsaturated esters and diastereoselective arylation of 4-substituted cyclohexyl esters. It is also involved in aromatic halide substitution reactions.Product classM-P, Homogeneous Catalysts, Monodentate Ligands, Phosphorus Ligands - AchiralReaction typeCross Coupling Reactions with Arenes, Alpha Arylation, Suzuki-Miyaura Coupling Reaction, IsomerizationChemical propertiesChemical formulaC24H54Br2P2Pd2Empirical formula[PdBr[P(tBu3)]]2Molecular weight777.29MetalPdTheoretical metal content27Physical statecrystallineColordark green

IUPAC Name：palladium;tritert-butylphosphane;bromide

INCHI：InChI=1S/C12H27P.BrH.Pd/c1-10(2,3)13(11(4,5)6)12(7,8)9;;/h1-9H3;1H;/p-1

InChi Key：WIADNXKBAGKNOT-UHFFFAOYSA-M

Canonical SMILES：CC(C)(C)P(C(C)(C)C)C(C)(C)C.[Br-].[Pd]

Isomeric SMILES：CC(C)(C)P(C(C)(C)C)C(C)(C)C.[Br-].[Pd]

WGK Germany：3

PubChem CID：71317307

溶解性：Soluble in benzene and tolueneSoluble in tetrahydrofuran, toluene, dichloromethane and chloroform. Insoluble in alcohols and water.

敏感性：对空气和热敏感

象形图：

信号词：Danger

危险声明：H315 Causes skin irritationH319 Causes serious eye irritationH335 May cause respiratory irritationH314 Causes severe skin burns and eye damageH250 Catches fire spontaneously if exposed to airH261 In contact with water releases flammable gas

预防措施声明：P261,P305+P351+P338,P280,P231+P232,P370+P378,P210,P302+P352,P321,P405,P501,P233,P264,P260,P222,P231,P271,P301+P330+P331,P304+P340,P363,P403+P233,P362+P364,P402+P404,P302+P335+P334,P264+P265,P305+P354+P338,P337+P317,P332+P317,P302+P361+P354,P316,P319

个人防护装备：Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges

产品包装