产品名称

英文名称：1-Bromopinacolone

同义词

1-Bromopinacolone、5469-26-1、1-Bromo-3,3-dimethylbutan-2-one、1-Bromo-3,3-dimethyl-2-butanone、Bromopinacolone、1-Bromopinacolin、Bromomethyl tert-butyl ketone、Bromopinacolin、Pivaloylmethyl bromide、tert-Butyl bromomethyl ketone、2-BUTANONE, 1-BROMO-3,3-DIMETHYL、1-溴特己酮、1-溴-3,3-二甲基-2-丁酮、溴甲基叔丁基酮、溴甲基叔丁基甲酮

产品性质

CAS编号：5469-26-1

分子式：C6H11BrO

分子量：179.06

Beilstein号：506485

MDL号：MFCD00000206

PubChem编号：21642

别名：1-溴特己酮|1-溴-3,3-二甲基-2-丁酮|溴甲基叔丁基酮|溴甲基叔丁基甲酮

英文别名：1-Bromopinacolone|5469-26-1|1-Bromo-3,3-dimethylbutan-2-one|1-Bromo-3,3-dimethyl-2-butanone|Bromopinacolone|1-Bromopinacolin|Bromomethyl tert-butyl ketone|Bromopinacolin|Pivaloylmethyl bromide|tert-Butyl bromomethyl ketone|2-BUTANONE, 1-BROMO-3,3-DIMETHYL

规格或纯度：≥97.0%

英文名称：1-Bromopinacolone

应用：It is the suitable reagent for the synthesis of a photolabile azido derivative of the kaurene oxidase inhibitor 1-(4- chlorophenyl)4,4-dimethyl-2-(1,2,4-triazol-1-yl) pentan-3-ol (paclobutrazol).It may be used as reagent in the synthesis of 2-t-butyl-6-benzoylimidazo[1,2-b]pyridazine.

储存温度：避光,-20°C储存,充氩

运输条件：超低温冰袋运输

产品介绍：It is an α-bromoketone-aldehyde.[1] Coupling of 1-bromopinacolone with various aldehyde electrophiles catalyzed by SmI2 has been reported.It acts as reversible competitive inhibitor for acetylcholinesterase, during hydrolysis of acetylcholine.It is the suitable reagent for the synthesis of a photolabile azido derivative of the kaurene oxidase inhibitor 1-(4- chlorophenyl)4,4-dimethyl-2-(1,2,4-triazol-1-yl) pentan-3-ol (paclobutrazol).It may be used as reagent in the synthesis of 2-t-butyl-6-benzoylimidazo[1,2-b]pyridazine.1-Bromopinacolone is an α-bromoketone-aldehyde. Coupling of 1-bromopinacolone with various aldehyde electrophiles catalyzed by SmI2 has been reported. It acts as reversible competitive inhibitor for acetylcholinesterase, during hydrolysis of acetylcholine.

IUPAC Name：1-bromo-3,3-dimethylbutan-2-one

INCHI：InChI=1S/C6H11BrO/c1-6(2,3)5(8)4-7/h4H2,1-3H3

InChi Key：SAIRZMWXVJEBMO-UHFFFAOYSA-N

Canonical SMILES：CC(C)(C)C(=O)CBr

Isomeric SMILES：CC(C)(C)C(=O)CBr

WGK Germany：3

RTECS：EL7010000

PubChem CID：21642

Reaxy-Rn：506485

溶解性：Insoluble in water.

密度：1.33

敏感性：对空气&光&热敏感

折光率：n20/D 1.466

闪点(℉)：167 °F

闪点(℃)：66°C(lit.)

沸点：188-194 °C

熔点：−10 °C

象形图：

信号词：Warning

危险声明：H315 Causes skin irritationH319 Causes serious eye irritationH335 May cause respiratory irritation

预防措施声明：P261,P305+P351+P338,P280,P302+P352,P321,P405,P501,P264,P271,P304+P340,P403+P233,P362+P364,P264+P265,P337+P317,P332+P317,P319

个人防护装备：Eyeshields， full-face respirator (US)， Gloves， multi-purpose combination respirator cartridge (US)， type ABEK (EN14387) respirator filter

产品包装