产品名称

英文名称：Chloro[(tri-tert-butylphosphine)-2-(2-aminobiphenyl)]palladium(II)

同义词

P(t-Bu)3 Pd G2、P(t-Bu)3 Pd G2

产品性质

CAS编号：1375325-71-5

分子式：C24H37ClNPPd

分子量：512.41

MDL号：MFCD21608496

PubChem编号：60201440

别名：P(t-Bu)3 Pd G2

英文别名：P(t-Bu)3 Pd G2

规格或纯度：98%

英文名称：Chloro[(tri-tert-butylphosphine)-2-(2-aminobiphenyl)]palladium(II)

应用：P(t-Bu)3 Pd G2 (Chloro[(tri-tert-butylphosphine)-2-(2-aminobiphenyl)] palladium(II), Pd/P(t-Bu)3) may be used as catalyst in the following studies . Synthesis of sterically hindered biaryls (tetra-ortho-substituted), via cross-coupling reactions of aryl chlorides. . Stille cross-couplings reactions of aryl chloride. . Synthesis of chloropeptin I, via Stille cross-coupling reaction. . Heck reaction. . Negishi cross-coupling reactions.

储存温度：充氩

运输条件：常规运输

产品介绍：P(t-Bu)3 Pd G2 (Chloro[(tri-tert-butylphosphine)-2-(2-aminobiphenyl)] palladium(II)) is a second generation (G2) precatalyst containing a biphenyl-based ligand. Product participates in various palladium catalyzed cross-coupling reactions, C-C, C-N and C-O bond formation reactions, and Suzuki-Miyaura coupling reactions. It generates active Pd catalyst at room temperature in the presence of weak phosphate or carbonate bases. It has been proposed as an active catalyst for use in Stille reactions of aryl halides (bromides and chlorides).P(t-Bu)3 Pd G2 (Chloro[(tri-tert-butylphosphine)-2-(2-aminobiphenyl)] palladium(II), Pd/P(t-Bu)3) may be used as catalyst in the following studies . Synthesis of sterically hindered biaryls (tetra-ortho-substituted), via cross-coupling reactions of aryl chlorides. . Stille cross-couplings reactions of aryl chloride. . Synthesis of chloropeptin I, via Stille cross-coupling reaction. . Heck reaction. . Negishi cross-coupling reactions.P(t-Bu)3 Pd G2 (Chloro[(tri-tert-butylphosphine)-2-(2-aminobiphenyl)] palladium(II)) is a second generation (G2) precatalyst containing a biphenyl-based ligand. Product participates in various palladium catalyzed cross-coupling reactions, C-C, C-N and C-O bond formation reactions, and Suzuki-Miyaura coupling reactions. It generates active Pd catalyst at room temperature in the presence of weak phosphate or carbonate bases. It has been proposed as an active catalyst for use in Stille reactions of aryl halides (bromides and chlorides).P(t-Bu)3 Pd G2 (Chloro[(tri-tert-butylphosphine)-2-(2-aminobiphenyl)] palladium(II), Pd/P(t-Bu)3) may be used as catalyst in the following studies . Synthesis of sterically hindered biaryls (tetra-ortho-substituted), via cross-coupling reactions of aryl chlorides. . Stille cross-couplings reactions of aryl chloride. . Synthesis of chloropeptin I, via Stille cross-coupling reaction. . Heck reaction. . Negishi cross-coupling reactions.

IUPAC Name：chloropalladium(1+);2-phenylaniline;tritert-butylphosphane

INCHI：InChI=1S/C12H10N.C12H27P.ClH.Pd/c13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-10(2,3)13(11(4,5)6)12(7,8)9;;/h1-6,8-9H,13H2;1-9H3;1H;/q-1;;;+2/p-1

InChi Key：DZNFQIYYEXFFGV-UHFFFAOYSA-M

Canonical SMILES：CC(C)(C)P(C(C)(C)C)C(C)(C)C.C1=CC=C([C-]=C1)C2=CC=CC=C2N.Cl[Pd+]

Isomeric SMILES：CC(C)(C)P(C(C)(C)C)C(C)(C)C.C1=CC=C([C-]=C1)C2=CC=CC=C2N.Cl[Pd+]

WGK Germany：3

PubChem CID：60201440

Reaxy-Rn：22750896

敏感性：空气及湿度敏感

熔点：167-170°C

象形图：

信号词：Warning

危险声明：H315 Causes skin irritationH319 Causes serious eye irritationH413 May cause long lasting harmful effects to aquatic lifeH302 Harmful if swallowedH228 Flammable solidH312 Harmful in contact with skinH332 Harmful if inhaledH290 May be corrosive to metals

预防措施声明：P261,P305+P351+P338,P273,P280,P370+P378,P210,P302+P352,P321,P501,P240,P264,P271,P241,P270,P304+P340,P362+P364,P330,P234,P390,P406,P264+P265,P301+P317,P317,P337+P317,P332+P317

产品包装