产品名称

英文名称：Diethyl azodicarboxylate

同义词

Diethyl azodicarboxylate、1972-28-7、DEAD、Diethoxycarbonyldiazene、Ethyl azodicarboxylate、Diethyl azodiformate、4143-61-7、Diethyl diazenedicarboxylate、azodicarboxylic acid diethyl ester、Azodiformic acid diethyl ester、Diethyl azodicarboxylate [MI]、ethyl (NE)-N

产品性质

CAS编号：1972-28-7

分子式：C6H10N2O4

分子量：174.15

Beilstein号：908662

MDL号：MFCD00009103

PubChem编号：5462977

英文别名：Diethyl azodicarboxylate|1972-28-7|DEAD|Diethoxycarbonyldiazene|Ethyl azodicarboxylate|Diethyl azodiformate|4143-61-7|Diethyl diazenedicarboxylate|azodicarboxylic acid diethyl ester|Azodiformic acid diethyl ester|Diethyl azodicarboxylate [MI]|ethyl (NE)-N

规格或纯度：97%

英文名称：Diethyl azodicarboxylate

储存温度：2-8°C储存,充氩

运输条件：冰袋运输

产品介绍：空气敏感。Diethyl azodicarboxylate acts as a dienophile used in Diels-Alder reactions. It is used as a reagent in alfa-thiocyanation of enolizable ketones with ammonium thiocyanate and annulation of N-protected imines. It acts as a reactant for the preparation of immunostimulants alfa-Galactosylceramides, bisubstrate inhibitors with molecular recognition at the active site of catechol-O-methyltransferase and aza-beta-lactams via NHC-catalyzed [2 + 2] cycloaddition with ketenes. It finds application in Mitsunobu reaction and used in the synthesis of pharmaceuticals like zidovudine and procarbazine. The presence of azo group in it is a Michael acceptor and used for the conversion of beta-ketoesters to the corresponding hydrazine derivatives in presence of copper(II) catalyst. Further, it is an efficient dehydrogenating agent, which is involved in the preparation of aldehydes, disulfides from alcohols and thiols respectively.

IUPAC Name：ethyl (NE)-N-ethoxycarbonyliminocarbamate

INCHI：InChI=1S/C6H10N2O4/c1-3-11-5(9)7-8-6(10)12-4-2/h3-4H2,1-2H3/b8-7+

InChi Key：FAMRKDQNMBBFBR-BQYQJAHWSA-N

Canonical SMILES：CCOC(=O)N=NC(=O)OCC

Isomeric SMILES：CCOC(=O)/N=N/C(=O)OCC

WGK Germany：3

PubChem CID：5462977

UN Number：1993

溶解性：Miscible with dichloromethane, diethyl ether and toluene.

密度：0.96

敏感性：对空气、光、热敏感

折光率：1.421

闪点(℉)：85℃

闪点(℃)：85℃

沸点：106°C

象形图：

信号词：Danger

危险声明：H315 Causes skin irritationH319 Causes serious eye irritationH335 May cause respiratory irritationH302 Harmful if swallowedH312 Harmful in contact with skinH332 Harmful if inhaledH240 Heating may cause an explosion

预防措施声明：P261,P305+P351+P338,P280,P210,P302+P352,P321,P405,P501,P240,P264,P271,P403,P270,P304+P340,P403+P233,P362+P364,P410,P420,P330,P234,P235,P411,P264+P265,P301+P317,P317,P337+P317,P332+P317,P319,P370+P372+P380+P373

个人防护装备：Eyeshields,Faceshields,full-face respirator (US),Gloves,multi-purpose combination respirator cartridge (US),type ABEK (EN14387) respirator filter

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