产品名称

英文名称：(tert-Butyldimethylsilyloxy)acetaldehyde

同义词

DTXSID40400520 、 STL557021 、 Acetaldehyde, [[(1,1-dimethylethyl)dimethylsilyl]oxy]- 、 B6269 、 BP-31208 、 tert-Butyldimethylsilyloxy)acetaldehyde 、 t-butyldimethylsiloxyacetaldehyde 、 BBL103211 、 BS-19212 、 SCHEMBL64584 、 [tert-butyl(dimethyl)silyl]oxy}ace、2-[(叔丁基二甲基硅基)氧基]乙醛 、 (叔丁基二甲基硅氧基)乙醛

产品性质

CAS编号：102191-92-4

分子式：(CH3)3CSi(CH3)2OCH2CHO

分子量：174.31

MDL号：MFCD01321229

PubChem编号：4187788

别名：2-[(叔丁基二甲基硅基)氧基]乙醛 | (叔丁基二甲基硅氧基)乙醛

英文别名：DTXSID40400520 | STL557021 | Acetaldehyde, [[(1,1-dimethylethyl)dimethylsilyl]oxy]- | B6269 | BP-31208 | tert-Butyldimethylsilyloxy)acetaldehyde | t-butyldimethylsiloxyacetaldehyde | BBL103211 | BS-19212 | SCHEMBL64584 | [tert-butyl(dimethyl)silyl]oxy}ace

规格或纯度：90%

英文名称：(tert-Butyldimethylsilyloxy)acetaldehyde

储存温度：2-8°C储存,充氩

运输条件：冰袋运输

产品介绍：(tert-Butyldimethylsilyloxy)acetaldehyde is used in tetrahydropyran subunit construction, yielding addition products in good amounts in various total syntheses of biologically active molecules.Used in tetrahydropyran subunit construction.Application(tert-Butyldimethylsilyloxy)acetaldehyde is a versatile reagent commonly used in synthetic glycobiology. It can act both as an aldol donor and an aldol acceptor in the stereocontrolled production of erythrose. It is used as an important reagent in the total synthesis of (+)-ambruticin, (−)-laulimalide, (−)-salinosporamide A, and (+)-leucascandrolide A.Employed in the construction of the key tetrahydropyran subunit in a recent synthesis of the marine natural product (–)-dactylodide.

PubChem SID：488194745

IUPAC Name：2-[tert-butyl(dimethyl)silyl]oxyacetaldehyde

INCHI：InChI=1S/C8H18O2Si/c1-8(2,3)11(4,5)10-7-6-9/h6H,7H2,1-5H3

InChi Key：MEBFFOKESLAUSJ-UHFFFAOYSA-N

Canonical SMILES：CC(C)(C)[Si](C)(C)OCC=O

Isomeric SMILES：CC(C)(C)[Si](C)(C)OCC=O

WGK Germany：3

PubChem CID：4187788

密度：0.93

敏感性：对湿度敏感；对热敏感

折光率：n20/D 1.432 (lit.)

闪点(℉)：140°F

闪点(℃)：60 °C

沸点：65 °C/17 mmHg

象形图：

信号词：Warning

危险声明：H315 Causes skin irritationH319 Causes serious eye irritationH335 May cause respiratory irritationH226 Flammable liquid and vapor

预防措施声明：P261,P305+P351+P338,P280,P370+P378,P210,P302+P352,P321,P405,P501,P233,P240,P264,P403+P235,P303+P361+P353,P271,P241,P304+P340,P403+P233,P362+P364,P242,P243,P264+P265,P337+P317,P332+P317,P319

个人防护装备：Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

产品包装