产品名称

英文名称：Ethyl 1,3-Dithiane-2-carboxylate

同义词

Ethyl 1,3-dithiane-2-carboxylate、20462-00-4、1,3-Dithiane-2-carboxylic acid ethyl ester、1,3-Dithiane-2-carboxylic acid, ethyl ester、Carboethoxy-1,3-dithiane、2-Carboethoxy-1,3-dithiane、DRA87T4JKT、m-Dithiane-2-carboxylic acid, ethyl ester、MFCD00006657、[1,3]d、1,3-二噻烷-2-甲酸乙酯、乙醛酸乙酯三亚甲基缩硫醛

产品性质

CAS编号：20462-00-4

分子式：C7H12O2S2

分子量：192.29

MDL号：MFCD00006657

PubChem编号：88552

别名：1,3-二噻烷-2-甲酸乙酯|乙醛酸乙酯三亚甲基缩硫醛

英文别名：Ethyl 1,3-dithiane-2-carboxylate|20462-00-4|1,3-Dithiane-2-carboxylic acid ethyl ester|1,3-Dithiane-2-carboxylic acid, ethyl ester|Carboethoxy-1,3-dithiane|2-Carboethoxy-1,3-dithiane|DRA87T4JKT|m-Dithiane-2-carboxylic acid, ethyl ester|MFCD00006657|[1,3]d

规格或纯度：>98.0%(GC)

英文名称：Ethyl 1,3-Dithiane-2-carboxylate

运输条件：常规运输

产品介绍：Ethyl 1,3-dithiane-2-carboxylate is an α-keto acid equivalent and bulky equivalent of acetate. It participates in syn-selective aldol reactions. It can be prepared from the reaction of ethyl diethoxyacetate and 1,3-propanedithiol in the presence of BF3/Et2O. Asymmetric oxidation of ethyl 1,3-dithiane-2-carboxylate by Modena protocol has been reported to afford trans bis-sulfoxide in 60% yield. Carbanion from ethyl 1,3-dithiane-2-carboxylate may be employed for the preparation of α-keto esters.Ethyl 1,3-dithiane-2-carboxylate is an α-keto acid equivalent and bulky equivalent of acetate. It participates in syn-selective aldol reactions. It can be prepared from the reaction of ethyl diethoxyacetate and 1,3-propanedithiol in the presence of BF3/Et2O. Asymmetric oxidation of ethyl 1,3-dithiane-2-carboxylate by Modena protocol has been reported to afford trans bis-sulfoxide in 60% yield. Carbanion from ethyl 1,3-dithiane-2-carboxylate may be employed for the preparation of α-keto esters.

IUPAC Name：ethyl 1,3-dithiane-2-carboxylate

INCHI：InChI=1S/C7H12O2S2/c1-2-9-6(8)7-10-4-3-5-11-7/h7H,2-5H2,1H3

InChi Key：ANEDZEVDORCLPM-UHFFFAOYSA-N

Canonical SMILES：CCOC(=O)C1SCCCS1

Isomeric SMILES：CCOC(=O)C1SCCCS1

WGK Germany：3

PubChem CID：88552

Reaxy-Rn：1424352

溶解性：Slightly miscible with water.

密度：1.221

折光率：1.5390 to 1.5410

闪点(℉)：131 °F

闪点(℃)：55°C

沸点：75-77 °C/0.2 mmHg

熔点：19-21℃

危险声明：H226 Flammable liquid and vapor

个人防护装备：Eyeshields， Faceshields， full-face respirator (US)， Gloves， multi-purpose combination respirator cartridge (US)， type ABEK (EN14387) respirator filter

产品包装