产品名称

英文名称：4′-Chloro-2,2′6′,2′′-terpyridine

同义词

4'-Chloro-2,2'6',2''-terpyridine、128143-89-5、4-chloro-2,6-dipyridin-2-ylpyridine、4'-Chloro-2,2'6',2'-terpyridine、4'-Chloro-2,2',6',2''-Terpyridine、CHEMBL2205805、4-Chloro-2,26,2-Terpyridine、4/'-Chloro-2,2/'6/',2/'/'-terpyridine、MFCD00191930、4'-chloro-2、4'-氯-α,α',α''-三吡啶

产品性质

CAS编号：128143-89-5

分子式：C15H10ClN3

分子量：267.71

MDL号：MFCD00191930

PubChem编号：667748

别名：4'-氯-α,α',α''-三吡啶

英文别名：4'-Chloro-2,2'6',2''-terpyridine|128143-89-5|4-chloro-2,6-dipyridin-2-ylpyridine|4'-Chloro-2,2'6',2'-terpyridine|4'-Chloro-2,2',6',2''-Terpyridine|CHEMBL2205805|4-Chloro-2,26,2-Terpyridine|4/'-Chloro-2,2/'6/',2/'/'-terpyridine|MFCD00191930|4'-chloro-2

规格或纯度：98%

英文名称：4′-Chloro-2,2′6′,2′′-terpyridine

运输条件：常规运输

备注：200mg、25g卖完停产，不再备货

产品介绍：Product Describtion4′-Chloro-2,2′6′,2′′-terpyridine (4′-Cltpy, Cltpy, Cl-terpy) is a tridentate ligand that contains a terpyridine (tpy) site with a Cl site at the 4 -position. It coordinates with various metal ions through these two sites to form different coordination polymers. Crystal structure study shows terpyridine unit of Cltpy adopts a trans, trans conformation. Mol-ecules assemble themselves into stacked columns along the b axis, with an inter-planar distance of 3.51?. It undergoes Williamson type ether reactions with α,ω-bishydroxy-functionalized poly(propylene oxide。 It undergoes Williamson type reaction with α-hydroxy-ω-carboxy-functionalized poly(ethylen-oxide) to afford monoterpyridine terminated telechelics.4′-Chloro-2,2′6′,2′′-terpyridine may be used in the preparation of the following mono- and bis-terpyridines bis-hydroxy-functionalized terpyridine cadmium(II) complex and a fullerene derivative 4-functionalized 2,2′6′,2′′-terpyridines, building blocks for novel supramolecular structures, such as double helicates, dendrimers, micelles and metallo-supramolecular polymersProduct Application4'-Chloro-2,2'6',2''-terpyridine is widely utilized in the field of supramolecular chemistry, which is used to manufacture double helicates, dendrimers, micelles and metallo-supramolecular polymers. It is used to synthesize the mono- and bis-terpyridines. It is actively involved in Williamson type ether reactions alpha,µ-bishydroxy-functionalized poly(propylene oxide).

PubChem SID：488191025

PubChem SID url：https//pubchem.ncbi.nlm.nih.gov/substance/488191025

IUPAC Name：4-chloro-2,6-dipyridin-2-ylpyridine

INCHI：InChI=1S/C15H10ClN3/c16-11-9-14(12-5-1-3-7-17-12)19-15(10-11)13-6-2-4-8-18-13/h1-10H

InChi Key：AHEMFMCEBIJRMU-UHFFFAOYSA-N

Canonical SMILES：C1=CC=NC(=C1)C2=CC(=CC(=N2)C3=CC=CC=N3)Cl

Isomeric SMILES：C1=CC=NC(=C1)C2=CC(=CC(=N2)C3=CC=CC=N3)Cl

WGK Germany：3

PubChem CID：667748

溶解性：Slightly soluble in water.

熔点：148-150°C

象形图：

信号词：Danger

危险声明：H315 Causes skin irritationH319 Causes serious eye irritationH335 May cause respiratory irritationH301 Toxic if swallowedH318 Causes serious eye damage

预防措施声明：P261,P305+P351+P338,P280,P302+P352,P321,P405,P501,P264,P271,P270,P304+P340,P403+P233,P362+P364,P330,P264+P265,P301+P316,P305+P354+P338,P317,P337+P317,P332+P317,P319

个人防护装备：dust mask type N95 (US), Eyeshields, Faceshields, Gloves

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