产品名称

英文名称：Triisopropylsilane

同义词

Triisopropylsilane、6485-79-6、6459-79-6、tris(propan-2-yl)silane、Benzenesulfonic acid,5-[(4-amino-1-naphthalenyl)azo]-2-[2-[4-[(2-hydroxy-1-naphthalenyl)azo]-2-sulfophenyl]ethenyl]-,disodium salt (9CI)、tri(propan-2-yl)silicon、Triisopropylsilane, 98%、triisop、三异丙基氢硅

产品性质

CAS编号：6485-79-6

分子式：C9H22Si

分子量：158.36

Beilstein号：1733718

MDL号：MFCD00009657

PubChem编号：6327611

别名：三异丙基氢硅

英文别名：Triisopropylsilane|6485-79-6|6459-79-6|tris(propan-2-yl)silane|Benzenesulfonic acid,5-[(4-amino-1-naphthalenyl)azo]-2-[2-[4-[(2-hydroxy-1-naphthalenyl)azo]-2-sulfophenyl]ethenyl]-,disodium salt (9CI)|tri(propan-2-yl)silicon|Triisopropylsilane, 98%|triisop

规格或纯度：98%

英文名称：Triisopropylsilane

储存温度：充氩

运输条件：常规运输

产品介绍：Triisopropylsilane is a highly selective reducing agent which can be used to prepare anti-1,2-diols.大体积异丙基（与乙基相比）能实现选择性更高的还原反?应（例如，异头 C-苯基缩酮的 β-选择性还原），但是不会降低它们的活性（例如，三甲基硅醚的三氟甲烷?磺酸酮催化型还原醚化）。 用于 Ni(O) N-杂环卡宾络合物催化的反式-1,2-二醇的高度非?对映选择性制备。Triisopropylsilane is a highly selective reducing agent which can be used to prepare anti-1,2-diols.The bulky isopropyl groups (vs. ethyl) allow for more selective reductions, e.g., beta-selective reduction of anomeric C-phenyl ketals, but do not diminish their activity (e.g. in the copper triflate catalyzed reductive etherification of trimethylsilyl ethers). Used in a highly diastereoelective preparation of anti-1,2-diols catalyzed by a Ni(O) N-heterocyclic carbene complex.

INCHI：InChI=1S/C9H21Si/c1-7(2)10(8(3)4)9(5)6/h7-9H,1-6H3

InChi Key：ZGYICYBLPGRURT-UHFFFAOYSA-N

Canonical SMILES：CC(C)[Si](C(C)C)C(C)C

Isomeric SMILES：CC(C)[Si](C(C)C)C(C)C

WGK Germany：3

PubChem CID：6327611

UN Number：1993

Reaxy-Rn：1733718

溶解性：Immiscible with water.

密度：0.773

敏感性：对湿度敏感

折光率：1.434

闪点(℉)：100.4 °F

闪点(℃)：38 °C

沸点：84-86 °C/35 mmHg (lit.)

熔点：99°F

象形图：

信号词：Warning

危险声明：H315 Causes skin irritationH319 Causes serious eye irritationH335 May cause respiratory irritationH226 Flammable liquid and vapor

预防措施声明：P261,P305+P351+P338,P280,P370+P378,P210,P302+P352,P321,P405,P501,P233,P240,P264,P403+P235,P303+P361+P353,P271,P241,P304+P340,P403+P233,P362+P364,P242,P243,P264+P265,P337+P317,P332+P317,P319

个人防护装备：Eyeshields,Faceshields,full-face respirator (US),Gloves,multi-purpose combination respirator cartridge (US),type ABEK (EN14387) respirator filter

产品包装