产品名称

英文名称：Tris(3,5-dimethylphenyl)phosphine

同义词

Tris(3,5-dimethylphenyl)phosphine、69227-47-0、tris(3,5-dimethylphenyl)phosphane、Tri-3,5-xylylphosphine、Phosphine, tris(3,5-dimethylphenyl)-、p(3,5-xylyl)3、tris(3,5-xylyl) phosphine、SCHEMBL503226、DTXSID5071969、XRALRSQLQXKXKP-UHFFFAOYSA-N、MFCD03094579、AKOS015

产品性质

CAS编号：69227-47-0

分子式：[(CH3)2C6H3]3P

分子量：346.44

MDL号：MFCD03094579

PubChem编号：112263

英文别名：Tris(3,5-dimethylphenyl)phosphine|69227-47-0|tris(3,5-dimethylphenyl)phosphane|Tri-3,5-xylylphosphine|Phosphine, tris(3,5-dimethylphenyl)-|p(3,5-xylyl)3|tris(3,5-xylyl) phosphine|SCHEMBL503226|DTXSID5071969|XRALRSQLQXKXKP-UHFFFAOYSA-N|MFCD03094579|AKOS015

规格或纯度：96%

英文名称：Tris(3,5-dimethylphenyl)phosphine

应用：Catalyst for 1Cu / diphosphine-catalyzed asymmetric hydrogenation of heteroaromatic ketones and enones 2Highly selective rhodium-catalyzed hydrogenation reactions 3 Classical versus kinetic resolution in preparation of privileged silicon-stereogenic silanaphthalenes. Used for kinetic resolution of donor-functionalized secondary alcohols via Cu-H-catalyzed stereoselective silylation by dehydrogenative Si-O coupling with Si-stereogenic silanes. Used for comparative studies of conformational rigidity of silicon-stereogenic silanes in asymmetric catalysis.

运输条件：常规运输

产品介绍：Catalyst for 1Cu / diphosphine-catalyzed asymmetric hydrogenation of heteroaromatic ketones and enones 2Highly selective rhodium-catalyzed hydrogenation reactions 3 Classical versus kinetic resolution in preparation of privileged silicon-stereogenic silanaphthalenes. Used for kinetic resolution of donor-functionalized secondary alcohols via Cu-H-catalyzed stereoselective silylation by dehydrogenative Si-O coupling with Si-stereogenic silanes. Used for comparative studies of conformational rigidity of silicon-stereogenic silanes in asymmetric catalysis.Catalyst for 1Cu / diphosphine-catalyzed asymmetric hydrogenation of heteroaromatic ketones and enones 2Highly selective rhodium-catalyzed hydrogenation reactions 3 Classical versus kinetic resolution in preparation of privileged silicon-stereogenic silanaphthalenes. Used for kinetic resolution of donor-functionalized secondary alcohols via Cu-H-catalyzed stereoselective silylation by dehydrogenative Si-O coupling with Si-stereogenic silanes. Used for comparative studies of conformational rigidity of silicon-stereogenic silanes in asymmetric catalysis.

IUPAC Name：tris(3,5-dimethylphenyl)phosphane

INCHI：InChI=1S/C24H27P/c1-16-7-17(2)11-22(10-16)25(23-12-18(3)8-19(4)13-23)24-14-20(5)9-21(6)15-24/h7-15H,1-6H3

InChi Key：XRALRSQLQXKXKP-UHFFFAOYSA-N

Canonical SMILES：CC1=CC(=CC(=C1)P(C2=CC(=CC(=C2)C)C)C3=CC(=CC(=C3)C)C)C

Isomeric SMILES：CC1=CC(=CC(=C1)P(C2=CC(=CC(=C2)C)C)C3=CC(=CC(=C3)C)C)C

WGK Germany：3

PubChem CID：112263

熔点：160-165°C

象形图：

信号词：Warning

危险声明：H302 Harmful if swallowed

预防措施声明：P501,P264,P270,P330,P301+P317

个人防护装备：dust mask type N95 (US), Eyeshields, Gloves

产品包装