产品名称

英文名称：Pentamethylcyclopentadienylrhodium(III) chloride dimer

同义词

Chiralyst P618、1,3-环戊二烯基-1,2,3,4,5-五甲基-铑配合物、二氯(五甲基环戊二烯基)铑(II)二聚体、二氯(五甲基环戊二烯基)铑二聚体、五甲基环戊二烯基氯化铑二聚体、四氯双(五甲基环戊二烯基)二铑

产品性质

CAS编号：12354-85-7

分子式：[Rh(C5Me5)Cl2]2

分子量：618.08

MDL号：MFCD00061552

别名：Chiralyst P618|1,3-环戊二烯基-1,2,3,4,5-五甲基-铑配合物|二氯(五甲基环戊二烯基)铑(II)二聚体|二氯(五甲基环戊二烯基)铑二聚体|五甲基环戊二烯基氯化铑二聚体|四氯双(五甲基环戊二烯基)二铑

规格或纯度：99%

英文名称：Pentamethylcyclopentadienylrhodium(III) chloride dimer

应用：Catalyst for Oxidative olefination reactions C-C bond cleavage of secondary alcohols Ortho C-H olefination of phenol derivatives Oxidative annulation of pyridines Oxidative ortho-acylation of benzamides with aldehydes via direct functionalization of the sp2 C-H bond Amidation reactions Reductive alkylation reactions

法律信息：Product of Umicore

储存温度：充氩

运输条件：常规运输

产品介绍：Catalyst for Oxidative olefination reactions C-C bond cleavage of secondary alcohols Ortho C-H olefination of phenol derivatives Oxidative annulation of pyridines Oxidative ortho-acylation of benzamides with aldehydes via direct functionalization of the sp2 C-H bond Amidation reactions Reductive alkylation reactionsCatalyst for Oxidative olefination reactions C-C bond cleavage of secondary alcohols Ortho C-H olefination of phenol derivatives Oxidative annulation of pyridines Oxidative ortho-acylation of benzamides with aldehydes via direct functionalization of the sp2 C-H bond Amidation reactions Reductive alkylation reactionsProduct classM-C, Homogeneous Catalysts, Arene/Aryl LigandsReaction typeHydrogenation, CH-Activation, Transfer Hydrogenation, OxidationChemical propertiesChemical formulaC20H30Cl4Rh2Empirical formula[Rh(C5Me5)Cl2]2Molecular weight618.08MetalRhTheoretical metal content33Physical statecrystallineColorred

INCHI：1S/2C10H15.4ClH.2Rh/c2*1-6-7(2)9(4)10(5)8(6)3;;;;;;/h2*1-5H3;4*1H;;/q;;;;;;2*+2/p-4

InChi Key：QNIVKTTWBMFSBR-UHFFFAOYSA-J

Canonical SMILES：Cl[Rh]Cl.Cl[Rh]Cl.C[C]1[C](C)[C](C)[C](C)[C]1C.C[C]2[C](C)[C](C)[C](C)[C]2C

WGK Germany：3

溶解性：Soluble in chloroform and acetone. Slightly soluble in tetrahydrofuran and methanol. Insoluble in water and diethylether

敏感性：空气及湿度敏感

熔点：>300°C

象形图：

信号词：Warning

危险声明：H315 Causes skin irritationH319 Causes serious eye irritationH335 May cause respiratory irritationH302+H312+H332 Harmful if swallowed, in contact with skin or if inhaled

预防措施声明：P261,P305+P351+P338,P280,P501,P312,P264,P271,P270,P304+P340,P337+P313,P362+P364,P332+P313,P301+P312,P301+P312+P330,P302+P352+P312,P304+P340+P312

个人防护装备：dust mask type N95 (US), Eyeshields, Gloves

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