产品名称

英文名称：(tert-Butoxycarbonylmethyl)triphenylphosphonium bromide

同义词

59159-39-6、(tert-Butoxycarbonylmethyl)triphenylphosphonium bromide、(2-(tert-Butoxy)-2-oxoethyl)triphenylphosphonium bromide、(tert-Butoxycarbonylmethyl)triphenylphosphanium bromide、MFCD00075527、[2-[(2-methylpropan-2-yl)oxy]-2-oxoethyl]-triphenylphosphanium、(叔丁氧基羰基甲基)溴化三苯基鏻

产品性质

CAS编号：59159-39-6

分子式：(CH3)3CO2CCH2P(C6H5)3Br

分子量：459.36

MDL号：MFCD00075527

PubChem编号：2733853

别名：(叔丁氧基羰基甲基)溴化三苯基鏻

英文别名：59159-39-6|(tert-Butoxycarbonylmethyl)triphenylphosphonium bromide|(2-(tert-Butoxy)-2-oxoethyl)triphenylphosphonium bromide|(tert-Butoxycarbonylmethyl)triphenylphosphanium bromide|MFCD00075527|[2-[(2-methylpropan-2-yl)oxy]-2-oxoethyl]-triphenylphosphanium

规格或纯度：≥98.0%(HPLC)

英文名称：(tert-Butoxycarbonylmethyl)triphenylphosphonium bromide

运输条件：常规运输

备注：5g卖完停产，不再备货

产品介绍：ApplicationReactant forRhodium-catalyzed asymmetric hydrogenation reactionsWittig reactionWittig methylenationPreparation of N-(phenylmethyl)-cis-pyrrolidinediacetic acid esters via double aza-Michael addition reactionStereoselective preparation of of α-fluoro-α,β-unsaturated esters via deprotonation, followed by fluorination and stereoselective Wittig olefination with aldehydesWittig chain extension reactions

PubChem SID：488192444

IUPAC Name：[2-[(2-methylpropan-2-yl)oxy]-2-oxoethyl]-triphenylphosphanium;bromide

INCHI：InChI=1S/C24H26O2P.BrH/c1-24(2,3)26-23(25)19-27(20-13-7-4-8-14-20,21-15-9-5-10-16-21)22-17-11-6-12-18-22;/h4-18H,19H2,1-3H3;1H/q+1;/p-1

InChi Key：ZGLFRTJDWWKIAK-UHFFFAOYSA-M

Canonical SMILES：CC(C)(C)OC(=O)C[P+](C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3.[Br-]

Isomeric SMILES：CC(C)(C)OC(=O)C[P+](C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3.[Br-]

WGK Germany：3

PubChem CID：2733853

Reaxy-Rn：4631405

溶解性：可溶于甲醇

熔点：176°C(dec.)(lit.)

象形图：

信号词：Warning

危险声明：H315 Causes skin irritationH319 Causes serious eye irritationH335 May cause respiratory irritation

预防措施声明：P261,P305+P351+P338,P280,P302+P352,P321,P405,P501,P264,P271,P304+P340,P403+P233,P362+P364,P264+P265,P337+P317,P332+P317,P319

个人防护装备：dust mask type N95 (US)， Eyeshields， Gloves

产品包装