产品名称

英文名称：Magnesium(II) Bis(trifluoromethanesulfonyl)imide

同义词

Bis(trifluoromethanesulfonyl)imide Magnesium(II) Salt 、 Magnesium bis(ditriflimide) 、 Magnesium(II) Triflimide 、 MgTFSI、双三氟甲基磺酰亚胺镁(II) 、 双(三氟甲磺酰亚胺)镁

产品性质

CAS编号：133395-16-1

分子式：C4F12MgN2O8S4

分子量：584.58

MDL号：MFCD14156020

PubChem编号：11851070

别名：双三氟甲基磺酰亚胺镁(II) | 双(三氟甲磺酰亚胺)镁

英文别名：Bis(trifluoromethanesulfonyl)imide Magnesium(II) Salt | Magnesium bis(ditriflimide) | Magnesium(II) Triflimide | MgTFSI

规格或纯度：>97.0%(T)

英文名称：Magnesium(II) Bis(trifluoromethanesulfonyl)imide

应用：Magnesium bis(trifluoromethylsulfonyl)imide is a strong Lewis acid and used as a catalyst in organic synthesis. It is an electrolyte, which shows high anodic stability used in rechargeable magnesium batteries.

储存温度：2-8°C储存,充氩

运输条件：冰袋运输

产品介绍：双（三氟甲基磺酰基酰亚胺）镁（Mg(TFSI)2）是一种强镁Lewis酸。它在有机合成中用作催化剂。例如，它可用于硝基胺与烯烃反应合成二氢吡唑。此外，Mg(TFSI)2 盐还可用于离子导电性研究、迁移数测量和凝胶聚合物电解质（GPE）系统的电化学性质研究。双（三氟甲基磺酰基酰亚胺）镁，也称为三氟甲磺酰亚胺镁，可作为无机催化剂用于各种有机反应，包括酚类和醇类的乙酰化、内酯和胺的氨解反应、硅氧炔烯与羰基化合物的[2 + 2]环加成、1,6-二烯的环异构化、Friedel-Crafts酰化以及香豆素的合成等。Magnesium bis(trifluoromethanesulfonimide) (Mg(TFSI)2) is a strong magnesium Lewis acid. It is used as a catalyst in organic synthesis. For instance, it is used in the synthesis of dihydropyrazoles by reaction of nitrilimines with alkenes. Additionally, Mg(TFSI)2 salt is also useful for ionic conductivity studies, transference number measurements, and electrochemical properties of gel polymer electrolyte (GPE) systems.Magnesium bis(trifluoromethanesulfonimide), also known as magnesium triflimide, can be used as an inorganic catalyst in various organic reactions, including acetylation of phenols and alcohols, aminolysis of lactones with amines, [2 + 2] cycloadditions of siloxy-alkynes with carbonyl compounds, cycloisomerization of 1,6-dienes, Friedel-Crafts acylation, and for the synthesis of coumarins.ApplicationMagnesium bis(trifluoromethylsulfonyl)imide is a strong Lewis acid and used as a catalyst in organic synthesis. It is an electrolyte, which shows high anodic stability used in rechargeable magnesium batteries.

IUPAC Name：magnesium;bis(trifluoromethylsulfonyl)azanide

INCHI：InChI=1S/2C2F6NO4S2.Mg/c2*3-1(4,5)14(10,11)9-15(12,13)2(6,7)8;/q2*-1;+2

InChi Key：DMFBPGIDUUNBRU-UHFFFAOYSA-N

Canonical SMILES：C(F)(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)F.C(F)(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)F.[Mg+2]

Isomeric SMILES：C(F)(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)F.C(F)(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)F.[Mg+2]

PubChem CID：11851070

UN Number：1759

Packing Group：II

Reaxy-Rn：9365509

溶解性：Insoluble in water.

敏感性：对湿度&空气&光线敏感

熔点：>200 °C

象形图：

信号词：Danger

危险声明：H314 Causes severe skin burns and eye damage

预防措施声明：P280,P321,P405,P501,P264,P260,P301+P330+P331,P304+P340,P363,P305+P354+P338,P302+P361+P354,P316

Class：8

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