产品名称

英文名称：(Acetylacetonato)dicarbonylrhodium(I)

同义词

CARAC、Rh(CO)2acac、乙酰丙酮二羰基铑(I)

产品性质

CAS编号：14874-82-9

分子式：Rh(CO)2(C5H7O2)

分子量：258.03

EC号：238-947-9

MDL号：MFCD00009884

PubChem编号：84819248

别名：CARAC|Rh(CO)2acac|乙酰丙酮二羰基铑(I)

规格或纯度：99%

英文名称：(Acetylacetonato)dicarbonylrhodium(I)

储存温度：室温,充氩

运输条件：常规运输

产品介绍：(Acetylacetonato)dicarbonylrhodium(I) is used in in situ formation of a fluorous-soluble hydroformylation catalyst of interest in molecular engineering. It is also used as a catalyst for various carbonylation reactions, silylcarbocyclizations,conjugate additions to enones, carbamoylstannation,and reduction of aromatic nitro compounds.A catalyst for various carbonylation reactionsProduct classM-O, Homogeneous Catalysts, Acetylacetonate LigandsReaction typeCarbonylation, Hydroformylation, ReductionChemical propertiesChemical formulaC7H7O4RhEmpirical formulaRh(CO)2(acac)Molecular weight258.04MetalRhTheoretical metal content40Physical statecrystallineColorgreen

INCHI：1S/C5H8O2.2CO.Rh/c1-4(6)3-5(2)7;2*1-2;/h3,6H,1-2H3;;;/q;;;+1/p-1/b4-3-;;;

InChi Key：BZCAWKOPWNIDOC-FGSKAQBVSA-M

Canonical SMILES：[C-]#[O+].[C-]#[O+].CC(=O)\C=C(\C)O[Rh]

Isomeric SMILES：CC(=[OH+])CC(=[OH+])C.[C-]#[O+].[C-]#[O+].[Rh]

WGK Germany：3

PubChem CID：84819248

UN Number：3467

溶解性：Solubility in water insoluble in water;Soluble in acetone

密度：0.94

敏感性：对空气敏感

熔点：154-156°C

象形图：

信号词：Warning

危险声明：H319 Causes serious eye irritationH317 May cause an allergic skin reactionH228 Flammable solid

预防措施声明：P305+P351+P338,P280,P210,P302+P352,P240,P241

个人防护装备：Risk of explosion if heated under confinement.

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