产品名称

英文名称：Dichloro[9,9-dimethyl-4,5-bis(diphenylphosphino)xanthene]palladium(II)

同义词

205319-10-4、DICHLORO[9,9-DIMETHYL-4,5-BIS(DIPHENYLPHOSPHINO)XANTHENE]PALLADIUM(II)、dichloropalladium;(5-diphenylphosphanyl-9,9-dimethylxanthen-4-yl)-diphenylphosphane、MFCD14155707、PdCl2(Xant-Phos)、SCHEMBL12466735、AMY41872、AKOS024462646、Dichloro[9,9-dimeth、Umicore CX97、[4,5-双(二苯基膦基)-9,9-二甲基氧杂蒽]二氯化钯(II)

产品性质

CAS编号：205319-10-4

分子式：C39H32Cl2OP2Pd

分子量：755.94

MDL号：MFCD14155707

PubChem编号：60153068

别名：Umicore CX97|[4,5-双(二苯基膦基)-9,9-二甲基氧杂蒽]二氯化钯(II)

英文别名：205319-10-4|DICHLORO[9,9-DIMETHYL-4,5-BIS(DIPHENYLPHOSPHINO)XANTHENE]PALLADIUM(II)|dichloropalladium;(5-diphenylphosphanyl-9,9-dimethylxanthen-4-yl)-diphenylphosphane|MFCD14155707|PdCl2(Xant-Phos)|SCHEMBL12466735|AMY41872|AKOS024462646|Dichloro[9,9-dimeth

规格或纯度：≥98.0%

英文名称：Dichloro[9,9-dimethyl-4,5-bis(diphenylphosphino)xanthene]palladium(II)

法律信息：Product of Umicore

储存温度：充氩

运输条件：常规运输

产品介绍：Effective catalyst for carbonylation of aryl halides.Effective catalyst for carbonylation of aryl halides.Product classM-P, Homogeneous Catalysts, Bidentate Ligands, Phosphorus Ligands - AchiralReaction typeHydrogenation, Transfer Hydrogenation, OxidationChemical propertiesChemical formulaC39H32Cl2OP2PdEmpirical formula[Pd(Xantphos)Cl2]Molecular weight755.94MetalPdTheoretical metal content14Physical statepowderColoryellowApplications & referencesEfficient oxidative carboxylation of benzylic C-H bonds via nondirected C(sp³)-H activation forming substituted 2-phenylacetic acid esters and derivatives starting from inexpensive, commercially available starting materials.Reference J. Am. Chem. Soc. 2012, 134, 9902 (10.1021/ja3036459)High yielding palladium catalyzed esterification of aryl halides using aryl formates without using external carbon monoxide.Reference Chem. Comm. 2012, 48, 8012 (DOI 10.1039/C2CC33944G)Palladium catalyzed carbonylation of allyl amines via C-N bond activation yielding β,γ-unsaturated amides under moderately mild reaction conditions.Reference RSC Adv. 2014, 4, 64235 (10.1039/c4ra13939a)

IUPAC Name：dichloropalladium;(5-diphenylphosphanyl-9,9-dimethylxanthen-4-yl)-diphenylphosphane

INCHI：InChI=1S/C39H32OP2.2ClH.Pd/c1-39(2)33-25-15-27-35(41(29-17-7-3-8-18-29)30-19-9-4-10-20-30)37(33)40-38-34(39)26-16-28-36(38)42(31-21-11-5-12-22-31)32-23-13-6-14-24-32;;;/h3-28H,1-2H3;2*1H;/q;;;+2/p-2

InChi Key：HEYONDYPXIUDCK-UHFFFAOYSA-L

Canonical SMILES：CC1(C2=C(C(=CC=C2)P(C3=CC=CC=C3)C4=CC=CC=C4)OC5=C1C=CC=C5P(C6=CC=CC=C6)C7=CC=CC=C7)C.Cl[Pd]Cl

Isomeric SMILES：CC1(C2=C(C(=CC=C2)P(C3=CC=CC=C3)C4=CC=CC=C4)OC5=C1C=CC=C5P(C6=CC=CC=C6)C7=CC=CC=C7)C.Cl[Pd]Cl

WGK Germany：3

PubChem CID：60153068

敏感性：对空气敏感

熔点：287 °C(dec.)

象形图：

信号词：Warning

危险声明：H315 Causes skin irritationH319 Causes serious eye irritationH335 May cause respiratory irritationH413 May cause long lasting harmful effects to aquatic lifeH302 Harmful if swallowedH317 May cause an allergic skin reactionH312 Harmful in contact with skinH332 Harmful if inhaledH290 May be corrosive to metals

预防措施声明：P261,P305+P351+P338,P273,P280,P302+P352,P321,P405,P501,P264,P271,P270,P304+P340,P403+P233,P272,P333+P313,P362+P364,P330,P234,P390,P406,P264+P265,P301+P317,P317,P337+P317,P332+P317,P319

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