产品名称

英文名称：(Bromodifluoromethyl)trimethylsilane

同义词

115262-01-6、(bromodifluoromethyl)trimethylsilane、TriMethyl(broModifluoroMethyl)silane、Silane, (bromodifluoromethyl)trimethyl-、[bromo(difluoro)methyl]-trimethylsilane、[Bromo(difluoro)methyl]trimethylsilane、MFCD18641931、[bromo(difluoro)methyl](trimethyl)sil、溴二氟(三甲基硅基)甲烷

产品性质

CAS编号：115262-01-6

分子式：C4H9BrF2Si

分子量：203.1

MDL号：MFCD18641931

PubChem编号：14639950

别名：溴二氟(三甲基硅基)甲烷

英文别名：115262-01-6|(bromodifluoromethyl)trimethylsilane|TriMethyl(broModifluoroMethyl)silane|Silane, (bromodifluoromethyl)trimethyl-|[bromo(difluoro)methyl]-trimethylsilane|[Bromo(difluoro)methyl]trimethylsilane|MFCD18641931|[bromo(difluoro)methyl](trimethyl)sil

规格或纯度：>98.0%(GC)

英文名称：(Bromodifluoromethyl)trimethylsilane

应用：(Bromodifluoromethyl)trimethylsilane may be used in the preparation of · gem-difluorocyclopropa(e)nes · O-, S-, N-, and P-difluoromethylated compounds · (chlorodifluoromethyl)trimethylsilane As reported by Hu and co-workers, (Bromodifluoromethyl)trimethylsilane is a highly useful reagent for the formation of difluoromethene-containing 3-membered rings and can also difluoromethylate heteroatoms with the assistance of alkaline bases, most effectively KOH.

储存温度：-20°C储存,充氩

运输条件：超低温冰袋运输

产品介绍：(Bromodifluoromethyl)trimethylsilane (TMSCF2Br) is commonly used as a source to generate dilfluorocarbene. TMSCF3 (Ruppert-Prakash reagent) and BBr3undergoes fast halogen-exchange reaction to form MSCF2Br.(Bromodifluoromethyl)trimethylsilane may be used in the preparation of · gem-difluorocyclopropa(e)nes · O-, S-, N-, and P-difluoromethylated compounds · (chlorodifluoromethyl)trimethylsilane As reported by Hu and co-workers, (Bromodifluoromethyl)trimethylsilane is a highly useful reagent for the formation of difluoromethene-containing 3-membered rings and can also difluoromethylate heteroatoms with the assistance of alkaline bases, most effectively KOH.(Bromodifluoromethyl)trimethylsilane (TMSCF2Br) is commonly used as a source to generate dilfluorocarbene. TMSCF3 (Ruppert-Prakash reagent) and BBr3undergoes fast halogen-exchange reaction to form MSCF2Br.

IUPAC Name：[bromo(difluoro)methyl]-trimethylsilane

INCHI：InChI=1S/C4H9BrF2Si/c1-8(2,3)4(5,6)7/h1-3H3

InChi Key：WDZVWBWAUSUTTO-UHFFFAOYSA-N

Canonical SMILES：C[Si](C)(C)C(F)(F)Br

Isomeric SMILES：C[Si](C)(C)C(F)(F)Br

PubChem CID：14639950

Reaxy-Rn：3535353

密度：1.306

敏感性：对空气、光线、热、湿度敏感

折光率：1.407

闪点(℃)：17 °C

沸点：108°C(lit.)

象形图：

信号词：Danger

危险声明：H315 Causes skin irritationH319 Causes serious eye irritationH335 May cause respiratory irritationH225 Highly Flammable liquid and vaporH226 Flammable liquid and vapor

预防措施声明：P261,P305+P351+P338,P280,P370+P378,P210,P302+P352,P321,P405,P501,P233,P240,P264,P403+P235,P303+P361+P353,P271,P241,P304+P340,P403+P233,P362+P364,P242,P243,P264+P265,P337+P317,P332+P317,P319

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