产品名称

英文名称：Iodotrimethylsilane

同义词

Iodotrimethylsilane、16029-98-4、Trimethyliodosilane、Trimethylsilyl iodide、iodo(trimethyl)silane、Silane, iodotrimethyl-、TMIS、7A65KRZ6NV、Iodotrimethylsilane; TMSI;Trimethylsilicon iodide; Trimethylsilyl iodide、trimethylsilyliodide、MFCD00001028、tms-iodide、iod、碘代三甲硅烷、三甲基硅基化碘、碘代三甲基硅烷

产品性质

CAS编号：16029-98-4

分子式：C3H9SiI

分子量：200.09

Beilstein号：1731136

EC号：240-171-0

MDL号：MFCD00001028

PubChem编号：85247

别名：碘代三甲硅烷|三甲基硅基化碘|碘代三甲基硅烷

英文别名：Iodotrimethylsilane|16029-98-4|Trimethyliodosilane|Trimethylsilyl iodide|iodo(trimethyl)silane|Silane, iodotrimethyl-|TMIS|7A65KRZ6NV|Iodotrimethylsilane; TMSI;Trimethylsilicon iodide; Trimethylsilyl iodide|trimethylsilyliodide|MFCD00001028|tms-iodide|iod

规格或纯度：97%,含铜作稳定剂

英文名称：Iodotrimethylsilane

应用：An efficient reagent for ether, ester, carbamate, ketal, and lactone cleavage；最近报道用于将烯丙基以及苄基磷酸三酯转化为相应的碘化物的试剂。 用于引入 TMS 基团，如 TMS 烯醇醚。用于在三甲基锡基存在的条件下对 N-Cbz 基团进行选择性脱保护的重要试剂。 用于裂解醚、酯、氨基甲酸盐、缩酮和内酯的有效试剂。

储存温度：-20°C储存,充氩

运输条件：超低温冰袋运输

产品介绍：三甲基碘硅烷是用于各种有机反应的多用途试剂。用于某些化合物（如内酯，醚，缩醛和氨基甲酸酯）的脱烷基化反应以及用作三甲基硅烷基化剂，用于合成硅烷基亚氨酸酯、烷基和烯基硅烷等。在许多有机反应中，还可用作路易斯（Lewis）酸催化剂和还原剂。 Iodotrimethylsilane is an efficient reagent for ether, ester, carbamate, ketal, and lactone cleavage.Reagent was recently reported to convert allyl- and benzylphosphotriesters to the corresponding iodides. For the introduction of the TMS group, e.g., TMS enol ethers.An efficient reagent for ether, ester, carbamate, ketal, and lactone cleavage；Efficient reagent for cleaving ethers, esters, carbamates, ketals, and lactones. For the introduction of the TMS group, e.g., TMS enol ethers.Key reagent for the selective deprotection of an N-Cbz group in the presence of a trimethyltin moiety. Reagent was recently reported to convert allyl- and benzylphosphotriesters to the corresponding iodides. Iodotrimethylsilane is used for the introduction of trimethylsilyl group in organic synthesis. It is also useful for gas chromatography analysis by converting alcohol into a silyl ether derivative, thereby making it more volatile than the original molecule.

IUPAC Name：iodo(trimethyl)silane

INCHI：InChI=1S/C3H9ISi/c1-5(2,3)4/h1-3H3

InChi Key：CSRZQMIRAZTJOY-UHFFFAOYSA-N

Canonical SMILES：C[Si](C)(C)I

Isomeric SMILES：C[Si](C)(C)I

WGK Germany：3

PubChem CID：85247

UN Number：2924

Reaxy-Rn：1731136

溶解性：Miscible with water.

密度：1.46

敏感性：对湿度和光敏感

折光率：1.47-1.48

闪点(℉)：28°F

闪点(℃)：-2℃

沸点：106°C

象形图：

信号词：Danger

危险声明：H314 Causes severe skin burns and eye damageH225 Highly Flammable liquid and vapor

预防措施声明：P280,P370+P378,P210,P321,P405,P501,P233,P240,P264,P403+P235,P260,P303+P361+P353,P241,P301+P330+P331,P304+P340,P363,P242,P243,P305+P354+P338,P302+P361+P354,P316

个人防护装备：Faceshields,full-face respirator (US),Gloves,Goggles,multi-purpose combination respirator cartridge (US),type ABEK (EN14387) respirator filter

产品包装