产品名称

英文名称：1,1'-Bis(di-tert-butylphosphino)ferrocene palladium dichloride

同义词

Umicore CX96、[1,1'-双(二叔丁基膦)二茂铁]二氯化钯( II )

产品性质

CAS编号：95408-45-0

分子式：C26H44Cl2FeP2Pd

分子量：651.77

MDL号：MFCD08064219

别名：Umicore CX96|[1,1'-双(二叔丁基膦)二茂铁]二氯化钯( II )

规格或纯度：98%

英文名称：1,1'-Bis(di-tert-butylphosphino)ferrocene palladium dichloride

储存温度：-20°C储存,充氩

运输条件：超低温冰袋运输

产品介绍：[1,1′-Bis(di-tert-butylphosphino)ferrocene]dichloropalladium(II) (PdCl2(dtbpf)) participates as catalyst in Suzuki and Heck reactions. It is a preformed catalyst synthesized by a group of researchers at Johnson Matthey′s Catalysis and Chiral Technologies. It is an active catalyst for various Pd catalyzed cross-coupling reactions.Application Guide for Palladium Catalyzed Cross-Coupling Reactions[1,1′-Bis(di-tert-butylphosphino)ferrocene]dichloropalladium(II) (PdCl2(dtbpf)) participates as catalyst in Suzuki and Heck reactions. It is a preformed catalyst synthesized by a group of researchers at Johnson Matthey′s Catalysis and Chiral Technologies. It is an active catalyst for various Pd catalyzed cross-coupling reactions.Application Guide for Palladium Catalyzed Cross-Coupling ReactionsProduct classM-P, Homogeneous Catalysts, M-C, Bidentate Ligands, Ferrocenyl Ligands - AchiralReaction typeCross Coupling Reactions with Arenes, Suzuki-Miyaura Coupling ReactionChemical propertiesChemical formulaC26H44Cl2FeP2PdEmpirical formula[Pd(dtbpf)Cl2]Molecular weight651.75MetalPdTheoretical metal content16Physical statecrystallineColorredApplications & referencesReductive carbonylation of aryl halides as an alternative and mild route for the introduction of aldehyde functionality, which is mostly desired for fine chemical and pharmaceutical intermediates to open up the wide range of further possible transformations.Reference Org. Proc. Res. Dev. 2007, 11, 39. (DOI 10.1021/op060193w)Total synthesis of diacyl glycerolacyltransferase-1 (DGAT-1) inhibitor including an ambient temperature Suzuki−Miyaura coupling reaction. DGAT-1 is one of two isoforms which catalyze the final and committed step of triglyceride biosynthesis. This compound could play a decisive role in the development of obesity and insulin resistance.Reference Org. Proc. Res. Dev. 2010, 14, 417 (DOI 10.1021/op900310v)High yielding Palladium catalyzed C-H arylation of electron-enriched heteroarenes with aryl bromides.Reference J. Org. Chem. 2010, 75, 6998. (DOI 10.1021/jo101433g)

WGK Germany：3

熔点：203-208°C

个人防护装备：Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter

产品包装