产品名称

英文名称：(R)-RuCl[(p-cymene)(BINAP)]Cl

同义词

130004-33-0、145926-28-9、(R)-RuCl[(p-cymene)(BINAP)]Cl、(S)-RuCl[(p-cymene(BINAP)]Cl、Chloro[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II) Chloride、(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENECHLORO(P-CYMENE)RUTHENIUM、Chiralyst Ru929、[(R)-(+)-2,2'-双(二苯基膦)-1,1'-联萘基](对伞花烃)氯化钌(II)氯化物

产品性质

CAS编号：145926-28-9

分子式：[C54H46ClP2Ru]+Cl-

分子量：928.87

MDL号：MFCD00134456

PubChem编号：11147374

别名：Chiralyst Ru929|[(R)-(+)-2,2'-双(二苯基膦)-1,1'-联萘基](对伞花烃)氯化钌(II)氯化物

英文别名：130004-33-0|145926-28-9|(R)-RuCl[(p-cymene)(BINAP)]Cl|(S)-RuCl[(p-cymene(BINAP)]Cl|Chloro[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II) Chloride|(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENECHLORO(P-CYMENE)RUTHENIUM

规格或纯度：>90.0%(HPLC)

英文名称：(R)-RuCl[(p-cymene)(BINAP)]Cl

储存温度：2-8°C储存,充氩

运输条件：冰袋运输

备注：500mg、100mg卖完停产，不再备货

产品介绍：Ligands and Complexes for Asymmetric Reactions.Product classM-P, Homogeneous Catalysts, M-C, Arene/Aryl Ligands, Phosphorus Ligands - ChiralReaction typeHydrogenation, Asymmetric Reactions, Asymmetric Hydrogenation, Transfer HydrogenationChemical propertiesChemical formulaC54H46Cl2P2RuEmpirical formula[RuCl(p-cymene)(R)-BINAP]ClMolecular weight928.88MetalRuTheoretical metal content11Physical statepowderColorred orangeApplications & referencesSynthesis of chiral acid derivatives by asymmetrical hydrogenation of the corresponding (E)-allylic ethers in the preparation of spiro-substituted glutaramide derivatives.Reference EP644176Asymmetric hydrogenation of halogenated acetophenones to enantiomerically pure halogenated phenyl ethanol derivatives.Reference Cat. Lett. 1996, 41, 111 (DOI 10.1007/BF00811721)Highly enantioselective catalytic hydrogenation of methyl-N-tertbutyl-3-oxoglutarate as a key step in the total synthesis of rovastatin.Reference Tetrah. Lett. 2008, 49, 4836 (DOI 10.1016/j.tetlet.2008.06.018)Enantioselective hydrogenation of 4-(hydroxymethyl)furan-2(5H)-one derivatives.Reference J. Mol. Cat. A Chem. 2006, 259, 103 (DOI 10.1016/j.molcata.2006.05.066)

IUPAC Name：dichlororuthenium;[1-(2-diphenylphosphanylnaphthalen-1-yl)naphthalen-2-yl]-diphenylphosphane;1-methyl-4-propan-2-ylbenzene

INCHI：InChI=1S/C44H32P2.C10H14.2ClH.Ru/c1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38;1-8(2)10-6-4-9(3)5-7-10;;;/h1-32H;4-8H,1-3H3;2*1H;/q;;;;+2/p-2

InChi Key：WNHLGYRPKARUHY-UHFFFAOYSA-L

Canonical SMILES：CC1=CC=C(C=C1)C(C)C.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=C(C4=CC=CC=C4C=C3)C5=C(C=CC6=CC=CC=C65)P(C7=CC=CC=C7)C8=CC=CC=C8.Cl[Ru]Cl

Isomeric SMILES：CC1=CC=C(C=C1)C(C)C.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=C(C4=CC=CC=C4C=C3)C5=C(C=CC6=CC=CC=C65)P(C7=CC=CC=C7)C8=CC=CC=C8.Cl[Ru]Cl

WGK Germany：3

PubChem CID：11147374

溶解性：不溶于水

敏感性：空气及湿度敏感

象形图：

信号词：Warning

危险声明：H315 Causes skin irritationH319 Causes serious eye irritationH335 May cause respiratory irritation

预防措施声明：P261,P305+P351+P338,P280,P302+P352,P321,P405,P501,P264,P271,P304+P340,P403+P233,P362+P364,P264+P265,P337+P317,P332+P317,P319

个人防护装备：Eyeshields， Gloves， type N95 (US)， type P1 (EN143) respirator filter

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