产品名称

英文名称：Rhodium(III) acetylacetonate

同义词

(E)-4-hydroxypent-3-en-2-one;rhodium 、 Rhodium acetylacetonate 、 MFCD00083144 、 Rhodium(III) 2,4-pentanedionate, Premion(R) 、 AKOS025311441 、 Rh(acac)3 、 2,4-Pentanedione rhodium(III) derivative、2,4-戊二酮 铑(III) 衍生物

产品性质

CAS编号：14284-92-5

分子式：[CH3COCH=C(O-)CH3]3Rh

分子量：400.23

EC号：238-192-5

MDL号：MFCD00083144

PubChem编号：71306774

别名：2,4-戊二酮 铑(III) 衍生物

英文别名：(E)-4-hydroxypent-3-en-2-one;rhodium | Rhodium acetylacetonate | MFCD00083144 | Rhodium(III) 2,4-pentanedionate, Premion(R) | AKOS025311441 | Rh(acac)3 | 2,4-Pentanedione rhodium(III) derivative

规格或纯度：99.99% metals basis

英文名称：Rhodium(III) acetylacetonate

运输条件：常规运输

产品介绍：Rhodium(III) acetylacetonate is a yellowcrystalline compound composed of rhodium atoms coordinated with three acetylacetonate ligands. It iswidely used in the field of catalysis, organic electronics and to prepare Rhcomplexes. It is soluble inorganic solvents.ApplicationRhodium(III) acetylacetonate can be used As a precursor to synthesize Rh nanocrystals with catalytic activities；As an efficient catalyst for the α-alkylation of ketones, β-alkylation of secondary alcohols, and the alkylation of amines with primary alcohols；To prepare highly phosphorescent complexes for organic light-emitting devices；To synthesize the Rh2P NCs supported on carbon (Rh2P/C) by a one-step solvothermal method via a direct reaction between Rh(acac)3 and tri-n-octylphosphine (TOP). The resultant electrocatalyst exhibited remarkable performance for both the hydrogen evolution reaction and the oxygen evolution reaction, surpassing the capabilities of Rh/C and Pt/C catalysts for water splitting；To prepare Single-atom Rh/N-doped carbon electrocatalyst for the oxidation of formic acid；To synthesize Pt–Rh NWs as highly efficient electrocatalysts toward ethanol oxidation reaction (EOR) for Direct ethanol fuel cells. The electrocatalyst demonstrated improved catalytic activities, primarily attributed to the presence of Rh, which enhances its ability to resist poisoning.

IUPAC Name：(E)-4-hydroxypent-3-en-2-one;rhodium

INCHI：InChI=1S/3C5H8O2.Rh/c3*1-4(6)3-5(2)7;/h3*3,6H,1-2H3;/b3*4-3+;

InChi Key：MBVAQOHBPXKYMF-MUCWUPSWSA-N

Canonical SMILES：CC(=CC(=O)C)O.CC(=CC(=O)C)O.CC(=CC(=O)C)O.[Rh]

Isomeric SMILES：C/C(=C\C(=O)C)/O.C/C(=C\C(=O)C)/O.C/C(=C\C(=O)C)/O.[Rh]

WGK Germany：3

PubChem CID：71306774

溶解性：Very soluble in chloroform. Soluble in alcohol. In soluble in water.

密度：0.852

熔点：263-264°C

象形图：

信号词：Warning

危险声明：H315 Causes skin irritationH319 Causes serious eye irritationH335 May cause respiratory irritationH302 Harmful if swallowedH312 Harmful in contact with skinH332 Harmful if inhaledH361 Suspected of damaging fertility or the unborn child

预防措施声明：P261,P305+P351+P338,P280,P302+P352,P321,P405,P501,P264,P271,P270,P304+P340,P403+P233,P362+P364,P330,P203,P264+P265,P301+P317,P318,P317,P337+P317,P332+P317,P319

个人防护装备：dust mask type N95 (US), Eyeshields, Gloves

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