产品名称

英文名称：N-Benzylquininium Chloride [Chiral Phase-Transfer Catalyst]

同义词

N-Benzylquininium chloride、67174-25-8、N-Benzylquininium chloride, 98%、(2S,4S,5R)-1-Benzyl-2-((R)-hydroxy(6-methoxyquinolin-4-yl)methyl)-5-vinylquinuclidin-1-ium chloride、SCHEMBL306470、N-Benzylquininium chloride, 95%、(1S,2S,4S,5R)-1-benzyl-2-((R)-hydroxy(6

产品性质

CAS编号：67174-25-8

分子式：C27H31ClN2O2

分子量：451.01

Beilstein号：5702637

MDL号：MFCD00198105

PubChem编号：10863314

英文别名：N-Benzylquininium chloride|67174-25-8|N-Benzylquininium chloride, 98%|(2S,4S,5R)-1-Benzyl-2-((R)-hydroxy(6-methoxyquinolin-4-yl)methyl)-5-vinylquinuclidin-1-ium chloride|SCHEMBL306470|N-Benzylquininium chloride, 95%|(1S,2S,4S,5R)-1-benzyl-2-((R)-hydroxy(6

规格或纯度：95%

英文名称：N-Benzylquininium Chloride [Chiral Phase-Transfer Catalyst]

运输条件：常规运输

备注：5g卖完停产，不再备货

产品介绍：N-Benzylquininium chloride (or Quibec) belongs to the class of cinchona family of alkaloids. It is used as a catalyst in the presence of hydroxide bases in various phase transfer reactions, epoxidations, alkylations, and Michael reactions.ApplicationN-Benzylquininium chloride can be used as a phase transfer catalystIn the sulfenylation of various β-keto sulfoxides.To synthesize N-carbamoyl-protected β-nitroamines from α-amido sulfones by asymmetric aza-Henry reaction.N-Benzylquininium chloride (or Quibec) belongs to the class of cinchona family of alkaloids. It is used as a catalyst in the presence of hydroxide bases in various phase transfer reactions, epoxidations, alkylations, and Michael reactions.ApplicationN-Benzylquininium chloride can be used as a phase transfer catalystIn the sulfenylation of various β-keto sulfoxides.To synthesize N-carbamoyl-protected β-nitroamines from α-amido sulfones by asymmetric aza-Henry reaction.

PubChem SID：488196866

IUPAC Name：(R)-[(1S,2S,4S,5R)-1-benzyl-5-ethenyl-1-azoniabicyclo[2.2.2]octan-2-yl]-(6-methoxyquinolin-4-yl)methanol;chloride

INCHI：InChI=1S/C27H31N2O2.ClH/c1-3-20-18-29(17-19-7-5-4-6-8-19)14-12-21(20)15-26(29)27(30)23-11-13-28-25-10-9-22(31-2)16-24(23)25;/h3-11,13,16,20-21,26-27,30H,1,12,14-15,17-18H2,2H3;1H/q+1;/p-1/t20-,21-,26-,27+,29+;/m0./s1

InChi Key：JYDIJFKNXHPWBJ-GOGFHWEMSA-M

Canonical SMILES：COC1=CC2=C(C=CN=C2C=C1)C(C3CC4CC[N+]3(CC4C=C)CC5=CC=CC=C5)O.[Cl-]

Isomeric SMILES：COC1=CC2=C(C=CN=C2C=C1)[C@H]([C@@H]3C[C@@H]4CC[N@+]3(C[C@@H]4C=C)CC5=CC=CC=C5)O.[Cl-]

WGK Germany：3

PubChem CID：10863314

Reaxy-Rn：14541607

比旋光度：227.5° (C=1.5,H2O)

熔点：200-205 °C (dec.) (lit.)

象形图：

信号词：Warning

危险声明：H315 Causes skin irritationH319 Causes serious eye irritation

预防措施声明：P305+P351+P338,P280,P302+P352,P321,P264,P362+P364,P264+P265,P337+P317,P332+P317

个人防护装备：Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter

产品包装