产品名称

英文名称：Wilkinson’s catalyst

同义词

14694-95-2、Chlorotris(triphenylphosphine)rhodium(I)、Tris(triphenylphosphine)rhodium(I) chloride、Wilkinson's catalyst、Tris(triphenylphosphine)chlororhodium、Chlorotris(triphenylphosphine)rhodium、16592-65-7、rhodium;triphenylphosphane;chloride、Tris(triphenylp、RhCl (PPh₃ ) ₃, Wilkinson 催化剂, NSC 124140, 三(三苯膦基)氯化铑(I)、氯化三(三苯基膦)铑(I)、威尔金森催化剂

产品性质

CAS编号：14694-95-2

分子式：C54H45ClP3Rh

分子量：925.22

Beilstein号：4581440

EC号：238-744-5

MDL号：MFCD00010016

PubChem编号：84599

别名：RhCl (PPh₃ ) ₃, Wilkinson 催化剂, NSC 124140, 三(三苯膦基)氯化铑(I)|氯化三(三苯基膦)铑(I)|威尔金森催化剂

英文别名：14694-95-2|Chlorotris(triphenylphosphine)rhodium(I)|Tris(triphenylphosphine)rhodium(I) chloride|Wilkinson's catalyst|Tris(triphenylphosphine)chlororhodium|Chlorotris(triphenylphosphine)rhodium|16592-65-7|rhodium;triphenylphosphane;chloride|Tris(triphenylp

规格或纯度：97%

英文名称：Wilkinson’s catalyst

储存温度：2-8°C储存,避光,充氩

运输条件：冰袋运输

产品介绍：空气中缓慢分解。不溶于水，溶于大多数溶剂，如苯、乙醇、丙酮、氯仿、二氯甲烷等，同时伴随膦的解离，溶液中会与氧发生反应。空气中缓慢分解。 1． 石蜡加氢催化剂 2． 在温和条件下进行催化加氢 3． 醛脱羰基反应催化剂 4． 丙烯的局部取代反应 5． 氧化、异构化、羰基化、氢化、硅氢化等反应。Product classM-P, Homogeneous Catalysts, Phosphorus Ligands - AchiralReaction typeCross Coupling Reactions with Arenes, Allylic Alkylation, C-H Activation, Carbonylation, Mizoroki Heck Coupling Reaction, Decarbonylation, Hydroformylation, Isomerization, Oligomerization, OxidationChemical propertiesChemical formulaC54H45ClP3RhEmpirical formulaRh(PPh3)3ClMolecular weight925.23MetalRhTheoretical metal content11Physical statecrystallineColorred

PubChem SID：488186262

PubChem SID url：https//pubchem.ncbi.nlm.nih.gov/substance/488186262

IUPAC Name：rhodium;triphenylphosphane;chloride

INCHI：InChI=1S/3C18H15P.ClH.Rh/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;/h3*1-15H;1H;/p-1

InChi Key：QBERHIJABFXGRZ-UHFFFAOYSA-M

Canonical SMILES：C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.[Cl-].[Rh]

Isomeric SMILES：C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.[Cl-].[Rh]

WGK Germany：3

PubChem CID：84599

UN Number：1759

Reaxy-Rn：14664394

溶解性：Soluble in most solvents (e.g. benzene, ethanol, chloroform, dichloromethane) but with phosphine dissociation. Reacts with O{2} in solution.

敏感性：对光、空气、热敏感

熔点：245-250°C

象形图：

信号词：Warning

危险声明：H411 Toxic to aquatic life with long lasting effectsH413 May cause long lasting harmful effects to aquatic lifeH302 Harmful if swallowedH317 May cause an allergic skin reaction

预防措施声明：P261,P273,P280,P302+P352,P321,P501,P264,P270,P272,P333+P313,P362+P364,P391,P330,P301+P317

Merck Index：9758

个人防护装备：Eyeshields,Gloves,type N95 (US),type P1 (EN143) respirator filter

产品包装