产品名称

英文名称：Chloroform-d

同义词

deuteriotrichloromethane 、 CDCl3 、 deuteriochloroform 、 Chloroform-D 、 Trichloromethane-d 、 (2H)Chloroform 、 Deuterochloroform 、 trichloro(deuterio)methane、deuterated chloroform 、 trichloro-Methaned、氘代氯仿 、 氯仿-d

产品性质

CAS编号：865-49-6

分子式：CDCl3

分子量：120.38

Beilstein号：1697633

EC号：212-742-4

MDL号：MFCD00000827

PubChem编号：71583

别名：氘代氯仿 | 氯仿-d

英文别名：deuteriotrichloromethane | CDCl3 | deuteriochloroform | Chloroform-D | Trichloromethane-d | (2H)Chloroform | Deuterochloroform | trichloro(deuterio)methane|deuterated chloroform | trichloro-Methaned

规格或纯度：(D,99.8%) +1% V/V TMS

英文名称：Chloroform-d

储存温度：避光,充氩

运输条件：常规运输

产品介绍：氯仿-d（氘代氯仿，CDCl 3 ）是氯仿的氘代衍生物。含有 1% (v/v) TMS（四甲基硅烷，作为稳定剂加入）。本文报道了氯仿-d 在不同有机溶剂中的碳氘伸缩峰的定量红外光谱研究。 用 Raman 差谱研究了氯仿-d 和液体氯仿混合物在 cCHCl3 和 CDCl3 的1 和 2 谱带中的频移。产品应用氯仿-d 已被用作氘代溶剂，用于含 α-苯乙基的 β-氨基丙酸相应手性衍生物的 NMR 谱研究，它们可作为 β-氨基酸不对称合成的有用起始原料。 Chloroform-d (Deuterochloroform, CDCl3) is adeuterated derivative of chloroform. It contains 1%(v/v) TMS (Tetramethylsilane, added as astabilizer). Quantitative infrared spectral investigations of carbon-deuterium stretching bands of chloroform-d in various organic solvents have been reported. Raman difference spectroscopic studies of mixtures of chloroform-d and liquid chloroform have been conducted to evaluate frequency shifts in the in the ν1 and ν2 bands of CHCl3 and CDCl3.ApplicationChloroform-d has been used as the deuterated solvent for the NMR spectral studies of the corresponding chiral derivatives of β-aminopropanoic acid containing the α-phenylethyl group, which serve as useful starting materials for the asymmetric synthesis of β-amino acids.

IUPAC Name：trichloro(deuterio)methane

INCHI：InChI=1S/CHCl3/c2-1(3)4/h1H/i1D

InChi Key：HEDRZPFGACZZDS-MICDWDOJSA-N

Canonical SMILES：C(Cl)(Cl)Cl

Isomeric SMILES：[2H]C(Cl)(Cl)Cl

WGK Germany：3

关联CAS：67-66-3（unlabelled）

PubChem CID：71583

UN Number：1888

Packing Group：III

密度：1.5

敏感性：对光，空气和湿度敏感

折光率：1.444

沸点：60.8°C

熔点：-64°C

象形图：

信号词：Danger

危险声明：H315 Causes skin irritationH319 Causes serious eye irritationH331 Toxic if inhaledH351 Suspected of causing cancerH373 Causes damage to organs through prolonged or repeated exposureH302 Harmful if swallowedH336 May cause drowsiness or dizzinessH372 Causes damage to organs through prolonged or repeated exposureH361 Suspected of damaging fertility or the unborn child

预防措施声明：P261,P305+P351+P338,P280,P302+P352,P321,P405,P501,P264,P260,P271,P270,P304+P340,P403+P233,P362+P364,P330,P203,P264+P265,P301+P317,P318,P337+P317,P332+P317,P316,P319

Class：6.1

个人防护装备：Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US)

产品包装