产品名称

英文名称：(R)-(+)-2,2′-Bis(diphenylphosphino)-1,1′-binaphthalene

同义词

98327-87-8、76189-55-4、76189-56-5、(R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl、BINAP、2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL、(S)-(-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl、(S)-BINAP、(S)-(-)-BINAP、2,2'-Bis(diphenylphosphino)-1,1'-binaphthale、(R)-(+)-BINAP、(R)-(+)-2,2'-联(二苯基膦基)-1,1'-联萘、(R)-(+)-2,2'-双(二苯基膦)-1,1'-联萘、(R)-(+)-BINAP, (R)-(+)-(1,1'-联萘-2,2'-二基)双(二苯膦)、(R)-(+)-2,2'-联(二苯基膦基)-1,1'-联萘

产品性质

CAS编号：76189-55-4

分子式：C44H32P2

分子量：622.67

MDL号：MFCD00010805

PubChem编号：634876

别名：(R)-(+)-BINAP|(R)-(+)-2,2'-联(二苯基膦基)-1,1'-联萘|(R)-(+)-2,2'-双(二苯基膦)-1,1'-联萘|(R)-(+)-BINAP, (R)-(+)-(1,1'-联萘-2,2'-二基)双(二苯膦)|(R)-(+)-2,2'-联(二苯基膦基)-1,1'-联萘

英文别名：98327-87-8|76189-55-4|76189-56-5|(R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl|BINAP|2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL|(S)-(-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl|(S)-BINAP|(S)-(-)-BINAP|2,2'-Bis(diphenylphosphino)-1,1'-binaphthale

规格或纯度：98%

英文名称：(R)-(+)-2,2′-Bis(diphenylphosphino)-1,1′-binaphthalene

储存温度：充氩

运输条件：常规运输

备注：50mg卖完停产，不再备货

产品介绍：产品介绍（R）-（+）-2,2′-双（二苯基膦基）-1,1′-双萘是用于不对称反应的轴向不对称双（三芳基）膦配体。产品应用过渡金属催化的不对称反应（包括氢化和二甲硅烷基化）的有用配体。2,2′-双（二苯基膦基）-1,1′-联萘基及其铑和钌衍生物是还原芳基酮、β-酮酸酯和 α-氨基酮的高选择性均相催化剂。它们也已用于烯烃的不对称氢化和加氢甲酰化，不对称 Heck 反应和烯丙基的不对称异构化。与 Ag（I）的络合物可用于催化烯基三氯乙酸酯和醛之间的不对称羟醛反应。也可与 Ag（I）一起催化偶氮化合物的对映选择性杂 Diels-Alder 反应。Product Introduction(R)-(+)-2,2′-Bis(diphenylphosphino)-1,1′-binaphthalene is an axially dissymmetric bis(triaryl)phosphine ligand for asymmetric reactions.ApplicationUseful ligand for transition metal catalyzed asymmetric reactions, including hydrogenation and disilylation. 2,2′-Bis(diphenylphosphino)-1,1′-binaphthyl and its rhodium and ruthenium derivatives are highly selective homogeneous catalysts used for the reduction of aryl ketones, β-keto esters, and α-amino ketones. They have also been used for asymmetric hydrogenation and hydroformylation of olefins, asymmetric Heck reactions, and asymmetric isomerizations of allyls.Complex with Ag(I) used to catalyze an asymmetric aldol reaction between alkenyl trichloroacetates and aldehydes. Also used with Ag(I) to catalyze an enantioselective hetero-Diels-Alder reaction of azo compounds.

PubChem SID：488190831

PubChem SID url：https//pubchem.ncbi.nlm.nih.gov/substance/488190831

IUPAC Name：[1-(2-diphenylphosphanylnaphthalen-1-yl)naphthalen-2-yl]-diphenylphosphane

INCHI：InChI=1S/C44H32P2/c1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38/h1-32H

InChi Key：MUALRAIOVNYAIW-UHFFFAOYSA-N

Canonical SMILES：C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=C(C4=CC=CC=C4C=C3)C5=C(C=CC6=CC=CC=C65)P(C7=CC=CC=C7)C8=CC=CC=C8

Isomeric SMILES：C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=C(C4=CC=CC=C4C=C3)C5=C(C=CC6=CC=CC=C65)P(C7=CC=CC=C7)C8=CC=CC=C8

WGK Germany：3

PubChem CID：634876

Reaxy-Rn：4914062

溶解性：Insoluble in water.

敏感性：对空气、湿度敏感

比旋光度：235 ° (C=0.3, Toluene)

熔点：239-242°C

象形图：

信号词：Warning

危险声明：H315 Causes skin irritationH319 Causes serious eye irritationH335 May cause respiratory irritationH413 May cause long lasting harmful effects to aquatic life

预防措施声明：P261,P305+P351+P338,P273,P280,P302+P352,P321,P405,P501,P264,P271,P304+P340,P403+P233,P362+P364,P264+P265,P337+P317,P332+P317,P319

个人防护装备：Eyeshields,Gloves,type N95 (US),type P1 (EN143) respirator filter

产品包装