产品名称

英文名称：Carbonyltris(triphenylphosphine)rhodium(I)hydride

同义词

17185-29-4、Carbonyltris(triphenylphosphine)rhodium(I) hydride、Carbonylhydridotris(triphenylphosphine)rhodium(I)、Hydridocarbonyltris(triphenylphosphine)rhodium(I)、Tris(triphenylphosphine)rhodium(I) carbonyl hydride、carbon monoxide;rhodium;triphenylphosphan、三苯基膦羰基氢化铑(I)、RhH(CO)(PPh3)3、铑单羰基氢三(三苯基膦)、三(三苯基膦)羰基铑氢化物、羰酰二氢三(三苯基膦)铑(I)、反式羰基(氢化)三(三苯基膦)铑、羰基氢化三(三苯基磷)铑(I)

产品性质

CAS编号：17185-29-4

分子式：C55H46OP3Rh

分子量：918.78

EC号：241-230-3

MDL号：MFCD00151644

PubChem编号：10941995

别名：三苯基膦羰基氢化铑(I)|RhH(CO)(PPh3)3|铑单羰基氢三(三苯基膦)|三(三苯基膦)羰基铑氢化物|羰酰二氢三(三苯基膦)铑(I)|反式羰基(氢化)三(三苯基膦)铑|羰基氢化三(三苯基磷)铑(I)

英文别名：17185-29-4|Carbonyltris(triphenylphosphine)rhodium(I) hydride|Carbonylhydridotris(triphenylphosphine)rhodium(I)|Hydridocarbonyltris(triphenylphosphine)rhodium(I)|Tris(triphenylphosphine)rhodium(I) carbonyl hydride|carbon monoxide;rhodium;triphenylphosphan

规格或纯度：97%

英文名称：Carbonyltris(triphenylphosphine)rhodium(I)hydride

储存温度：充氩,干燥

运输条件：常规运输

产品介绍：Tris(triphenylphosphine)rhodium(I) carbonyl hydride is a homogeneous catalyst which catalyzes the ring-opening isomerization of methylenecyclopropanes to 1,3-dienes.氢化、硅氢化、异构化、羰基化、加氢甲酰化、氧化等反应。催化亚甲基环丙烷类化合物进行开环异构化反应，生成 1,3-二烯类化合物。Tris(triphenylphosphine)rhodium(I) carbonyl hydride is a homogeneous catalyst which catalyzes the ring-opening isomerization of methylenecyclopropanes to 1,3-dienes.A homogeneous catalyst,Hydrogenation, hydrosilation, isomerization, carbonylation, hydroformylation, oxidation

IUPAC Name：carbon monoxide;rhodium;triphenylphosphane

INCHI：InChI=1S/3C18H15P.CO.Rh/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2;/h3*1-15H;;

InChi Key：IETKMTGYQIVLRF-UHFFFAOYSA-N

Canonical SMILES：[C-]#[O+].C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.[Rh]

Isomeric SMILES：[C-]#[O+].C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.[Rh]

WGK Germany：1

PubChem CID：10941995

UN Number：2811

溶解性：不溶于水。溶于碳氢化合物（如苯、甲苯等），同时伴随膦配位体的离解。

密度：1.27

敏感性：对空气敏感;对湿度敏感

熔点：150°C

象形图：

信号词：Danger

危险声明：H315 Causes skin irritationH319 Causes serious eye irritationH335 May cause respiratory irritationH301 Toxic if swallowedH311 Toxic in contact with skinH331 Toxic if inhaled

预防措施声明：P261,P305+P351+P338,P280,P302+P352,P321,P405,P501,P264,P271,P270,P304+P340,P403+P233,P362+P364,P330,P361+P364,P264+P265,P301+P316,P337+P317,P332+P317,P316,P319

Merck Index：9758

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