产品名称

英文名称：(DHQ)2PHAL

同义词

(DHQ)2PHAL、140924-50-1、1217464-63-5、AD-mix-alpha、1-((1R)-((2R,4R,5S)-5-ethylquinuclidin-2-yl)(6-methoxyquinolin-4-yl)methoxy)-4-((1R)-((2R,4S,5R)-5-ethylquinuclidin-2-yl)(6-methoxyquinolin-4-yl)methoxy)phthalazine、Hydroquinine 1,4-phthalazinediyl diether

产品性质

CAS编号：140924-50-1

分子式：C48H54N6O4

分子量：778.98

Beilstein号：5475677

MDL号：MFCD00191975

PubChem编号：51003674

英文别名：(DHQ)2PHAL|140924-50-1|1217464-63-5|AD-mix-alpha|1-((1R)-((2R,4R,5S)-5-ethylquinuclidin-2-yl)(6-methoxyquinolin-4-yl)methoxy)-4-((1R)-((2R,4S,5R)-5-ethylquinuclidin-2-yl)(6-methoxyquinolin-4-yl)methoxy)phthalazine|Hydroquinine 1,4-phthalazinediyl diether|

规格或纯度：95%

英文名称：(DHQ)2PHAL

运输条件：常规运输

产品介绍：配体，用于不饱和酯和三取代 C=C 键的非对称二羟基化。Sharpless 不对称双羟基化的配体，用于由 (E,E)- 或 (E,Z)-1,3-二烯酸甲酯不对称制备 syn-3,5-羟基羧酸酯。General descriptionDHQ)2PHAL is a modified cinchona alkaloid.application(DHQ)2PHAL may be used in the following processesAs a catalyst Asymmetric and chemoselective N-allylic alkylation of indoles with Morita-Baylis-Hillman carbonates to form pyrrolo[1,2-a]indole and pyrrolo[3,2,1-ij]quinoline derivatives.As a ligand for the osmium catalyzed-Sharpless asymmetric dihydroxylation step of (S)-a-benzoyloxy carboxylic acids multistep synthesis.As a ligand for the carbamate based asymmetric aminohydroxylation of styrene derivatives to form N-carbamate protected R-arylglycinols.

PubChem SID：488201476

IUPAC Name：4-[(R)-[(2R,4R,5S)-5-ethyl-1-azabicyclo[2.2.2]octan-2-yl]-(6-methoxyquinolin-4-yl)methoxy]-1-[(R)-[(2R,4S,5R)-5-ethyl-1-azabicyclo[2.2.2]octan-2-yl]-(6-methoxyquinolin-4-yl)methoxy]phthalazine

INCHI：InChI=1S/C48H54N6O4/c1-5-29-27-53-21-17-31(29)23-43(53)45(35-15-19-49-41-13-11-33(55-3)25-39(35)41)57-47-37-9-7-8-10-38(37)48(52-51-47)58-46(44-24-32-18-22-54(44)28-30(32)6-2)36-16-20-50-42-14-12-34(56-4)26-40(36)42/h7-16,19-20,25-26,29-32,43-46H,5-6,17-18,21-24,27-28H2,1-4H3/t29-,30+,31-,32+,43-,44-,45-,46-/m1/s1

InChi Key：YUCBLVFHJWOYDN-PPIALRKJSA-N

Canonical SMILES：CCC1CN2CCC1CC2C(C3=C4C=C(C=CC4=NC=C3)OC)OC5=NN=C(C6=CC=CC=C65)OC(C7CC8CCN7CC8CC)C9=C1C=C(C=CC1=NC=C9)OC

Isomeric SMILES：CC[C@@H]1CN2CC[C@@H]1C[C@@H]2[C@@H](C3=C4C=C(C=CC4=NC=C3)OC)OC5=NN=C(C6=CC=CC=C65)O[C@@H]([C@H]7C[C@@H]8CCN7C[C@@H]8CC)C9=C1C=C(C=CC1=NC=C9)OC

WGK Germany：3

PubChem CID：51003674

密度：1.3

熔点：178°C

象形图：

信号词：Warning

危险声明：H317 May cause an allergic skin reaction

预防措施声明：P261,P280,P302+P352,P321,P501,P272,P333+P313,P362+P364

个人防护装备：Eyeshields,Faceshields,Gloves,type N95 (US),type P1 (EN143) respirator filter

产品包装