产品名称

英文名称：Bismuth Chloride

同义词

FT-0623130 、 Bismuth(III) chloride 、 SY010298 、 UNII-4X6566U3SD 、 F21251 、 DTXSID3064851 、 AKOS015902592 、 Bismuth(III) chloride, reagent grade, >=98% 、 BiCl3 、 bismuth (III) chloride、三氯化铋 、 三氯铋 、 氯化铋 (III)

产品性质

CAS编号：7787-60-2

分子式：BiCl3

分子量：315.34

EC号：232-123-2

MDL号：MFCD00003461

PubChem编号：24591

别名：三氯化铋 | 三氯铋 | 氯化铋 (III)

英文别名：FT-0623130 | Bismuth(III) chloride | SY010298 | UNII-4X6566U3SD | F21251 | DTXSID3064851 | AKOS015902592 | Bismuth(III) chloride, reagent grade, >=98% | BiCl3 | bismuth (III) chloride

规格或纯度：Reagent Grade

英文名称：Bismuth Chloride

应用：制造铋盐，有机反应催化剂，高纯材料。 Bismuth(III) chloride may be used as a catalyst in the following processes · Alcoholysis, acetolysis and hydrolysis of epoxides to form the corresponding β-alkoxy and β-acetoxy alcohols and diols. · Preparation of thiiranes from oxiranes using ammonium thiocyanate. · Three component coupling of carbonyl compound, amine and dialkyl phosphite to form α-amino phosphonates. · Allylation of secondary benzyl alcohols with allyltrimethylsilane. · [4 + 2] cycloaddition between dienes and α-carbonyl ethylenic dienophiles.

储存温度：充氩

运输条件：常规运输

产品介绍：有氯化氢气味，具溶解性。加热则挥发，约在430℃时升华。在水中分解成氧氯化铋，能溶于盐酸、硝酸、无水乙醇、丙酮和乙酸乙酯。 制造铋盐，有机反应催化剂，高纯材料。应用 氯化铋 (III) 可作为催化剂用于以下过程醇解、乙酰化和环氧化物水解生成相应的的 β-烷氧基和 β-乙酰氧基醇和二醇。用硫氰酸铵从环氧乙烷制备噻吩。羰基化合物、胺和亚磷酸二烷基酯三组分偶联生成 α-氨基膦酸盐。烯丙基三甲基硅烷与仲苯甲醇的烯丙基化反应。[4 + 2] 二烯烃与α-羰基烯二烯烃之间的环加成反应。Bismuth(III) chloride is an inorganic salt that can be prepared by the reaction of bismuth with chlorine. Bismuth(III) chloride may be used as a catalyst in the following processes · Alcoholysis, acetolysis and hydrolysis of epoxides to form the corresponding β-alkoxy and β-acetoxy alcohols and diols. · Preparation of thiiranes from oxiranes using ammonium thiocyanate. · Three component coupling of carbonyl compound, amine and dialkyl phosphite to form α-amino phosphonates. · Allylation of secondary benzyl alcohols with allyltrimethylsilane. · [4 + 2] cycloaddition between dienes and α-carbonyl ethylenic dienophiles.

PubChem SID：488182904

PubChem SID url：https//pubchem.ncbi.nlm.nih.gov/substance/488182904

IUPAC Name：trichlorobismuthane

INCHI：InChI=1S/Bi.3ClH/h;3*1H/q+3;;;/p-3

InChi Key：JHXKRIRFYBPWGE-UHFFFAOYSA-K

Canonical SMILES：Cl[Bi](Cl)Cl

Isomeric SMILES：Cl[Bi](Cl)Cl

WGK Germany：2

RTECS：EB2690000

PubChem CID：24591

密度：4.75

敏感性：对湿度敏感

沸点：447°C

熔点：230°C

象形图：

信号词：Warning

危险声明：H315 Causes skin irritationH319 Causes serious eye irritation

预防措施声明：P305+P351+P338,P280,P302+P352,P321,P264,P362+P364,P264+P265,P337+P317,P332+P317

Merck Index：1262

个人防护装备：dust mask type N95 (US),Eyeshields,Gloves

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