产品名称

英文名称：RuCl[(R,R)-TsDPEN](mesitylene)

同义词

174813-82-2、RuCl[(R,R)-TsDPEN](mesitylene)、[N-[(1R,2R)-2-(Amino-kN)-1,2- diphenylethyl]-4-methylbenzenesulfonamidato-kN]chloro [(1,2,3,4,5,6-n)-1,3,5-trimethylbenzene]-ruthenium、Chloro(mesitylene)[(R,R)-N-(p-toluenesulfonyl)-1,2-diphenylethylenediamine]ru、[(R,R)-TsDPEN-Ru(均三甲苯)Cl]、[N-[(1R,2R)-2-(氨基-κN)-1,2-二苯乙基]-4-甲基苯磺酰胺合-κN]氯[(1,2,3,4,5,6-η)-1,3,5-三甲苯]-钌、[(R,R)-N-(2-氨基-1,2-二苯乙基)-对甲苯磺酰胺]氯化(均三甲苯)钌(II)、氯化(均三甲苯)[(R,R)-N-(对甲苯磺酰基)-1,2-二苯乙烯基二胺]钌(II)

产品性质

CAS编号：174813-82-2

分子式：C30H33ClN2O2RuS

分子量：622.18

MDL号：MFCD12545951

PubChem编号：91972075

别名：[(R,R)-TsDPEN-Ru(均三甲苯)Cl]|[N-[(1R,2R)-2-(氨基-κN)-1,2-二苯乙基]-4-甲基苯磺酰胺合-κN]氯[(1,2,3,4,5,6-η)-1,3,5-三甲苯]-钌|[(R,R)-N-(2-氨基-1,2-二苯乙基)-对甲苯磺酰胺]氯化(均三甲苯)钌(II)|氯化(均三甲苯)[(R,R)-N-(对甲苯磺酰基)-1,2-二苯乙烯基二胺]钌(II)

英文别名：174813-82-2|RuCl[(R,R)-TsDPEN](mesitylene)|[N-[(1R,2R)-2-(Amino-kN)-1,2- diphenylethyl]-4-methylbenzenesulfonamidato-kN]chloro [(1,2,3,4,5,6-n)-1,3,5-trimethylbenzene]-ruthenium|Chloro(mesitylene)[(R,R)-N-(p-toluenesulfonyl)-1,2-diphenylethylenediamine]ru

规格或纯度：≥90.0% (HPLC)

英文名称：RuCl[(R,R)-TsDPEN](mesitylene)

应用：Ligands and Complexes for Asymmetric Reactions RuCl[(R,R)-TsDPEN](mesitylene) may be used as a catalyst to synthesize · (2R,3S)-4-Benzyl-2-(hydroxyphenylmethyl)morpholin-3-one from racemic N-benzyl-2-benzoyl-3-morpholinone via dynamic kinetic resolution-based asymmetric transfer hydrogenation (ATH). · Chiral nonracemic δ-phenylseleno alcohols from δ-phenylseleno ketones via catalytic ATH reaction.

储存温度：2-8°C储存,充氩

运输条件：冰袋运输

产品介绍：Ligands and Complexes for Asymmetric ReactionsRuCl[(R,R)-TsDPEN](mesitylene) may be used as a catalyst to synthesize· (2R,3S)-4-Benzyl-2-(hydroxyphenylmethyl)morpholin-3-one from racemic N-benzyl-2-benzoyl-3-morpholinone via dynamic kinetic resolution-based asymmetric transfer hydrogenation (ATH).· Chiral nonracemic δ-phenylseleno alcohols from δ-phenylseleno ketones via catalytic ATH reaction.Ligands and Complexes for Asymmetric ReactionsRuCl[(R,R)-TsDPEN](mesitylene) may be used as a catalyst to synthesize· (2R,3S)-4-Benzyl-2-(hydroxyphenylmethyl)morpholin-3-one from racemic N-benzyl-2-benzoyl-3-morpholinone via dynamic kinetic resolution-based asymmetric transfer hydrogenation (ATH).· Chiral nonracemic δ-phenylseleno alcohols from δ-phenylseleno ketones via catalytic ATH reaction.

IUPAC Name：[(1R,2R)-2-amino-1,2-diphenylethyl]-(4-methylphenyl)sulfonylazanide;ruthenium(2+);1,3,5-trimethylbenzene;chloride

INCHI：InChI=1S/C21H21N2O2S.C9H12.ClH.Ru/c1-16-12-14-19(15-13-16)26(24,25)23-21(18-10-6-3-7-11-18)20(22)17-8-4-2-5-9-17;1-7-4-8(2)6-9(3)5-7;;/h2-15,20-21H,22H2,1H3;4-6H,1-3H3;1H;/q-1;;;+2/p-1/t20-,21-;;;/m1.../s1

InChi Key：XBNBOGZUDCYNOJ-AGEKDOICSA-M

Canonical SMILES：CC1=CC=C(C=C1)S(=O)(=O)[N-]C(C2=CC=CC=C2)C(C3=CC=CC=C3)N.CC1=CC(=CC(=C1)C)C.[Cl-].[Ru+2]

Isomeric SMILES：CC1=CC=C(C=C1)S(=O)(=O)[N-][C@H](C2=CC=CC=C2)[C@@H](C3=CC=CC=C3)N.CC1=CC(=CC(=C1)C)C.[Cl-].[Ru+2]

WGK Germany：3

PubChem CID：91972075

敏感性：对空气敏感;对热敏感;对湿度敏感

熔点：241-249 °C

象形图：

信号词：Warning

危险声明：H361 Suspected of damaging fertility or the unborn childH371 May cause damage to organs

预防措施声明：P280,P405,P501,P264,P260,P270,P203,P318,P308+P316

个人防护装备：Eyeshields， Gloves， type N95 (US)， type P1 (EN143) respirator filter

产品包装