产品名称

英文名称：(R)-1-[(SP)-2-(Diphenylphosphino)ferrocenyl]ethyldicyclohexylphosphine

同义词

(2R)-1-[(1R)-1-(二环己基膦)乙基]-2-(二苯基膦)二茂铁

产品性质

CAS编号：155806-35-2

分子式：C36H44FeP2C36H44FeP2 · C2H5OH

分子量：640.6

MDL号：MFCD00800284

PubChem编号：277390229

别名：(2R)-1-[(1R)-1-(二环己基膦)乙基]-2-(二苯基膦)二茂铁

规格或纯度：≥97%

英文名称：(R)-1-[(SP)-2-(Diphenylphosphino)ferrocenyl]ethyldicyclohexylphosphine

储存温度：充氩

运输条件：常规运输

产品介绍：(R)-1-[(SP)-2-(Diphenylphosphino)ferrocenyl]ethyldicyclohexylphosphine ((R,S)-josiphos) is a chiral ferrocenyl diphosphine ligand.It may be used in the preparation of cyclopentadienyliridium complexes, [IrCl(PP)]2 and [IrCp(PP)]. (Cp= cyclopentadienyl; PP= (R)-1-[(SP)-2-(diphenylphosphino)ferrocenyl]ethyldicyclohexylphosphine).(R)-1-[(SP)-2-(Diphenylphosphino)ferrocenyl]ethyldicyclohexylphosphine ((R,S)-josiphos) is a chiral ferrocenyl diphosphine ligand.

INCHI：1S/C31H39P2.C5H5.Fe/c1-25(32(26-15-6-2-7-16-26)27-17-8-3-9-18-27)30-23-14-24-31(30)33(28-19-10-4-11-20-28)29-21-12-5-13-22-29;1-2-4-5-3-1;/h4-5,10-14,19-27H,2-3,6-9,15-18H2,1H3;1-5H;/t25-;;/m1../s1

InChi Key：HGTBZFMPHBAUCQ-KHZPMNTOSA-N

Canonical SMILES：[Fe].[CH]1[CH][CH][CH][CH]1.C[C@H]([C]2[CH][CH][CH][C]2P(c3ccccc3)c4ccccc4)P(C5CCCCC5)C6CCCCC6

WGK Germany：3

PubChem CID：277390229

比旋光度：-360° (c 0.5, CHCl3)

个人防护装备：Eyeshields， Gloves， type N95 (US)， type P1 (EN143) respirator filter

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