产品名称

英文名称：Bis(norbornadiene)rhodium(I) tetrafluoroborate

同义词

Bis(norbornadiene)rhodium(I) tetrafluoroborate、36620-11-8、Bis[eta-(2,5-norbornadiene)]rhodium(I) Tetrafluoroborate、[rh(nbd)2]bf4、bicyclo[2.2.1]hepta-2,5-diene;rhodium;tetrafluoroborate、Rh(nbd)2BF4、Chiralyst P374、MFCD00671775、DTXSID30448239、ZWPWNBFOFVFMPP-、双(降冰片二烯)铑 (I) 四氟硼酸盐、双(双环[2.2.1]庚-2,5-二烯)四氟硼酸铑、双(降冰片二烯)(四氟硼酸)铑、双[η-(2,5-二环庚二烯)]四氟硼酸铑(I)

产品性质

CAS编号：36620-11-8

分子式：C14H16BF4Rh

分子量：373.99

MDL号：MFCD00671775

PubChem编号：10915722

别名：双(降冰片二烯)铑 (I) 四氟硼酸盐|双(双环[2.2.1]庚-2,5-二烯)四氟硼酸铑|双(降冰片二烯)(四氟硼酸)铑|双[η-(2,5-二环庚二烯)]四氟硼酸铑(I)

英文别名：Bis(norbornadiene)rhodium(I) tetrafluoroborate|36620-11-8|Bis[eta-(2,5-norbornadiene)]rhodium(I) Tetrafluoroborate|[rh(nbd)2]bf4|bicyclo[2.2.1]hepta-2,5-diene;rhodium;tetrafluoroborate|Rh(nbd)2BF4|Chiralyst P374|MFCD00671775|DTXSID30448239|ZWPWNBFOFVFMPP-

规格或纯度：27.5%

英文名称：Bis(norbornadiene)rhodium(I) tetrafluoroborate

储存温度：充氩

运输条件：常规运输

产品介绍：ApplicationPrecatalysts for Asymmetric and Cross-Coupling CatalysisBis(norbornadiene)rhodium(I) tetrafluoroborate can be used as a catalyst for the synthesis of• Lactones via the 1,4-addition of arylboronic acids to butenolide.• Chiral β-aryl-substituted ketones and esters.• β-aryloxycarboxylic esters from β-aryloxy-α,γ-unsaturated esters.Product classM-C, Homogeneous Catalysts, Diene/Dienyl LigandsReaction typeHydrogenation, Asymmetric Reactions, CH-Activation, Asymmetric Hydrogenation, IsomerizationChemical propertiesChemical formulaC14H16BF4RhEmpirical formula[Rh(nbd)2]BF4Molecular weight373.99MetalRhTheoretical metal content28Physical statepowderColorred

IUPAC Name：bicyclo[2.2.1]hepta-2,5-diene;rhodium;tetrafluoroborate

INCHI：InChI=1S/2C7H8.BF4.Rh/c2*1-2-7-4-3-6(1)5-7;2-1(3,4)5;/h2*1-4,6-7H,5H2;;/q;;-1;

InChi Key：ZWPWNBFOFVFMPP-UHFFFAOYSA-N

Canonical SMILES：[B-](F)(F)(F)F.C1C2C=CC1C=C2.C1C2C=CC1C=C2.[Rh]

Isomeric SMILES：[B-](F)(F)(F)F.C1C2C=CC1C=C2.C1C2C=CC1C=C2.[Rh]

WGK Germany：3

PubChem CID：10915722

UN Number：1759

敏感性：对空气敏感；对湿度敏感

熔点：136.9-139.9 °C

象形图：

信号词：Danger

危险声明：H315 Causes skin irritationH319 Causes serious eye irritationH335 May cause respiratory irritationH314 Causes severe skin burns and eye damageH302 Harmful if swallowed

预防措施声明：P261,P305+P351+P338,P280,P302+P352,P321,P405,P501,P264,P260,P271,P270,P301+P330+P331,P304+P340,P363,P403+P233,P362+P364,P330,P264+P265,P301+P317,P305+P354+P338,P337+P317,P332+P317,P302+P361+P354,P316,P319

个人防护装备：Eyeshields, Faceshields, Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges

产品包装