产品名称

英文名称：Allylpalladium(II) chloride dimer

同义词

Allylpalladium(II) chloride dimer、allylpalladium(II) chloride、MFCD00044874、Allylpalladium(II)chloride dimer、Bis(allyl)dichlorodipalladium、Palladium allyl chloride dimer、Diallydichlorodipalladium、pi-Allyl palladium chloride、Diallyldipalladium dichloride、Bi、[Pd(allyl)Cl]2、烯丙基氯化钯(II)二聚体, [氯化钯(C3H5)] 2, \ [氯化钯(烯丙基)] 2, 二烯丙基二氯二钯, 双(烯丙基氯钯), 双(烯丙基)二氯二钯, 双(烯丙基)二氯化钯, 烯丙基氯钯二聚体、氯化烯丙基钯(II)二聚物、二-μ-氯双[(η-烯丙基)钯(II)]

产品性质

CAS编号：12012-95-2

分子式：C6H10Cl2Pd2

分子量：365.89

Beilstein号：4124623

EC号：234-579-8

MDL号：MFCD00044874

PubChem编号：61538

别名：[Pd(allyl)Cl]2|烯丙基氯化钯(II)二聚体, [氯化钯(C3H5)] 2, \ [氯化钯(烯丙基)] 2, 二烯丙基二氯二钯, 双(烯丙基氯钯), 双(烯丙基)二氯二钯, 双(烯丙基)二氯化钯, 烯丙基氯钯二聚体|氯化烯丙基钯(II)二聚物|二-μ-氯双[(η-烯丙基)钯(II)]

英文别名：Allylpalladium(II) chloride dimer|allylpalladium(II) chloride|MFCD00044874|Allylpalladium(II)chloride dimer|Bis(allyl)dichlorodipalladium|Palladium allyl chloride dimer|Diallydichlorodipalladium|pi-Allyl palladium chloride|Diallyldipalladium dichloride|Bi

规格或纯度：Pd 58.2%

英文名称：Allylpalladium(II) chloride dimer

储存温度：2-8°C储存,避光,充氩,干燥

运输条件：冰袋运输

产品介绍：溶于氯仿、二氯甲烷，水中分解。对空气和潮湿敏感。 1.烯烃对映选择性氢化硅烷化的预催化剂。 2.环丙烯基醋酸盐不对称烷化和氨化的预催化剂。 3.交叉耦联反应催化剂。 4.二聚体可以用作Trost配体。 5.作为高对映选择性烯丙基烷化和氨化的有用前体。 6.烯烃甲锡烷基化催化剂。Allylpalladium(II) chloride dimer is employed as catalyst in Heck reaction. It also participates as catalyst in the tandem nucleophilic allylation-alkoxyallylation reaction of the alkynylaldehydes with allyl chloride and allyltributylstannane.Allylpalladium(II) chloride dimer has been employed for the following studies● Synthesis of cationic palladium cataysts, used in the microwave-assisted Heck arylation.● Synthesis of N-heterocyclic carbene-palladium-η3-allyl chloride complexes, which are efficient catalyst for the Suzuki-Miyaura cross-coupling of aryl bromides and activated aryl chlorides.● Synthesis of 1,4-diallyl-1,2-dihydroisoquinolines.● As catalyst for greener Buchwald-Hartwig coupling in TPGS-750-M.ApplicationPrecatalysts for Asymmetric and Cross-Coupling CatalysisProduct classM-C, Homogeneous Catalysts, Allyl LigandsReaction typeCross Coupling Reactions with Arenes, Amination, Allylic Alkylation, Buchwald-Hartwig Aminaton, Asymmetric Reactions, CH-Activation, Mizoroki Heck Coupling ReactionChemical propertiesChemical formulaC6H10Cl2Pd2Empirical formula[Pd(allyl)Cl]2Molecular weight365.89MetalPdTheoretical metal content58Physical statecrystallineColoryellow

IUPAC Name：chloropalladium(1+);prop-1-ene

INCHI：InChI=1S/2C3H5.2ClH.2Pd/c2*1-3-2;;;;/h2*3H,1-2H2;2*1H;;/q2*-1;;;2*+2/p-2

InChi Key：PENAXHPKEVTBLF-UHFFFAOYSA-L

Canonical SMILES：[CH2-]C=C.[CH2-]C=C.Cl[Pd+].Cl[Pd+]

Isomeric SMILES：[CH2-]C=C.[CH2-]C=C.Cl[Pd+].Cl[Pd+]

WGK Germany：3

RTECS：RT3510000

PubChem CID：61538

溶解性：不溶于水；可溶于丙酮、苯、甲醇、氯仿

密度：6.68

敏感性：对光敏感、对潮湿敏感

熔点：120°C

象形图：

信号词：Warning

危险声明：H315 Causes skin irritationH319 Causes serious eye irritationH335 May cause respiratory irritationH302 Harmful if swallowedH317 May cause an allergic skin reaction

预防措施声明：P261,P305+P351+P338,P280,P302+P352,P321,P405,P501,P264,P271,P270,P304+P340,P403+P233,P272,P333+P313,P362+P364,P330,P264+P265,P301+P317,P337+P317,P332+P317,P319

个人防护装备：dust mask type N95 (US),Eyeshields,Faceshields,full-face particle respirator type N100 (US),Gloves,respirator cartridge type N100 (US),type P1 (EN143) respirator filter,type P3 (EN 143) respirator cartridges

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