产品名称

英文名称：Chloro(1,5-cyclooctadiene)iridium(I) dimer

同义词

12112-67-3、Chloro(1,5-cyclooctadiene)iridium(I) dimer、Bis(1,5-cyclooctadiene)diiridium(I) dichloride、(1Z,5Z)-cycloocta-1,5-diene;iridium;dichloride、Iridium, di-.mu.-chlorobis[(1,2,5,6-.eta.)-1,5-cyclooctadiene]di-、MFCD00012414、Chloro(1,5-cyclooctadiene) i、Umicore HS157、双(1,5-环辛二烯)二铱(I)二氯化物, [Ir(1,5-cod)Cl]2, \ [铱 (1,5-cod) Cl] 2, \ [铱 (cod) Cl] 2, 二-μ-氯双[(1,2,5,6-η)-1,5-环辛二烯]二铱, 氯代-1,5-环戊二烯铱二聚体, 氯化铱(I) 1,5-环辛二烯络合物二聚体

产品性质

CAS编号：12112-67-3

分子式：C16H24Cl2Ir2

分子量：671.71

EC号：235-170-7

MDL号：MFCD00012414

PubChem编号：6436381

别名：Umicore HS157|双(1,5-环辛二烯)二铱(I)二氯化物, [Ir(1,5-cod)Cl]2, \ [铱 (1,5-cod) Cl] 2, \ [铱 (cod) Cl] 2, 二-μ-氯双[(1,2,5,6-η)-1,5-环辛二烯]二铱, 氯代-1,5-环戊二烯铱二聚体, 氯化铱(I) 1,5-环辛二烯络合物二聚体

英文别名：12112-67-3|Chloro(1,5-cyclooctadiene)iridium(I) dimer|Bis(1,5-cyclooctadiene)diiridium(I) dichloride|(1Z,5Z)-cycloocta-1,5-diene;iridium;dichloride|Iridium, di-.mu.-chlorobis[(1,2,5,6-.eta.)-1,5-cyclooctadiene]di-|MFCD00012414|Chloro(1,5-cyclooctadiene) i

规格或纯度：97%

英文名称：Chloro(1,5-cyclooctadiene)iridium(I) dimer

储存温度：-20°C储存

运输条件：超低温冰袋运输

产品介绍：A metal precursor for asymmetric allylic substitutions.ApplicationPre-catalysts for asymmetry and cross-coupling catalysisProduct classM-C, Homogeneous Catalysts, Diene/Dienyl LigandsReaction typeHydrogenation, Allylic Alkylation, Asymmetric Reactions, CH-Activation, Hydroamination, Asymmetric Hydrogenation, Transfer Hydrogenation, Hydrosilylation, ReductionChemical propertiesChemical formulaC16H24Cl2Ir2Empirical formula[Ir(cod)Cl]2Molecular weight671.71MetalIrTheoretical metal content57Physical statecrystallineColordark red

PubChem SID：488195780

IUPAC Name：(1Z,5Z)-cycloocta-1,5-diene;iridium;dichloride

INCHI：InChI=1S/2C8H12.2ClH.2Ir/c2*1-2-4-6-8-7-5-3-1;;;;/h2*1-2,7-8H,3-6H2;2*1H;;/p-2/b2*2-1-,8-7-;;;;

InChi Key：SHZHQWGWORCBJK-MIXQCLKLSA-L

Canonical SMILES：C1CC=CCCC=C1.C1CC=CCCC=C1.[Cl-].[Cl-].[Ir].[Ir]

Isomeric SMILES：C1/C=C\CC/C=C\C1.C1/C=C\CC/C=C\C1.[Cl-].[Cl-].[Ir].[Ir]

WGK Germany：3

PubChem CID：6436381

Reaxy-Rn：14372408

溶解性：不溶于水

敏感性：对空气敏感，对热敏感

熔点：205°C

象形图：

信号词：Warning

危险声明：H315 Causes skin irritationH319 Causes serious eye irritationH335 May cause respiratory irritationH302 Harmful if swallowedH312 Harmful in contact with skin

预防措施声明：P261,P305+P351+P338,P280,P302+P352,P321,P405,P501,P264,P271,P270,P304+P340,P403+P233,P362+P364,P330,P264+P265,P301+P317,P317,P337+P317,P332+P317,P319

个人防护装备：dust mask type N95 (US), Eyeshields, Gloves

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