产品名称

英文名称：(S,S)-DACH-naphthyl Trost Ligand

同义词

205495-66-5、N,N'-((1S,2S)-Cyclohexane-1,2-diyl)bis(2-(diphenylphosphino)-1-naphthamide)、(S,S)-DACH-naphthyl Trost Ligand、(1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL)、1-Naphthalenecarboxamide, N,N'-(1S,2S)-1,2-cyclohexanediy、(1S,2S)-(–)-1,2-二氨基环己烷-N,N'-双(2-二苯基膦-1-萘酰基)、(1S,2S)-(-)-N,N'-双(2-二苯基膦基-1-萘酰基)-1,2-环己二胺

产品性质

CAS编号：205495-66-5

分子式：C52H44N2O2P2

分子量：790.87

MDL号：MFCD02684552

PubChem编号：11767928

别名：(1S,2S)-(–)-1,2-二氨基环己烷-N,N'-双(2-二苯基膦-1-萘酰基)|(1S,2S)-(-)-N,N'-双(2-二苯基膦基-1-萘酰基)-1,2-环己二胺

英文别名：205495-66-5|N,N'-((1S,2S)-Cyclohexane-1,2-diyl)bis(2-(diphenylphosphino)-1-naphthamide)|(S,S)-DACH-naphthyl Trost Ligand|(1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL)|1-Naphthalenecarboxamide, N,N'-(1S,2S)-1,2-cyclohexanediy

规格或纯度：95%

英文名称：(S,S)-DACH-naphthyl Trost Ligand

应用：不对称烯丙基烷化反应的配体.

运输条件：常规运输

产品介绍：不对称烯丙基烷化反应的配体.Asymmetric allylic alkylation ligand

IUPAC Name：2-diphenylphosphanyl-N-[(1S,2S)-2-[(2-diphenylphosphanylnaphthalene-1-carbonyl)amino]cyclohexyl]naphthalene-1-carboxamide

INCHI：InChI=1S/C52H44N2O2P2/c55-51(49-43-29-15-13-19-37(43)33-35-47(49)57(39-21-5-1-6-22-39)40-23-7-2-8-24-40)53-45-31-17-18-32-46(45)54-52(56)50-44-30-16-14-20-38(44)34-36-48(50)58(41-25-9-3-10-26-41)42-27-11-4-12-28-42/h1-16,19-30,33-36,45-46H,17-18,31-32H2,(H,53,55)(H,54,56)/t45-,46-/m0/s1

InChi Key：VXFKMKXTPXVEMU-ZYBCLOSLSA-N

Canonical SMILES：C1CCC(C(C1)NC(=O)C2=C(C=CC3=CC=CC=C32)P(C4=CC=CC=C4)C5=CC=CC=C5)NC(=O)C6=C(C=CC7=CC=CC=C76)P(C8=CC=CC=C8)C9=CC=CC=C9

Isomeric SMILES：C1CC[C@@H]([C@H](C1)NC(=O)C2=C(C=CC3=CC=CC=C32)P(C4=CC=CC=C4)C5=CC=CC=C5)NC(=O)C6=C(C=CC7=CC=CC=C76)P(C8=CC=CC=C8)C9=CC=CC=C9

WGK Germany：3

PubChem CID：11767928

比旋光度：-66.0°, c=1 in methanol

熔点：232-237°C

产品包装