产品名称

英文名称：Methyl 3-Bromobenzoate

同义词

METHYL 3-BROMOBENZOATE、618-89-3、3-Bromobenzoic Acid Methyl Ester、Methyl m-bromobenzoate、Benzoic acid, 3-bromo-, methyl ester、3-Bromobenzoic acid, methyl ester、Benzoic acid, m-bromo-, methyl ester、3-bromo-benzoic acid methyl ester、MFCD00017777、methyl-3-bro、间溴苯甲酸甲酯

产品性质

CAS编号：618-89-3

分子式：C8H7BrO2

分子量：215.05

Beilstein号：9(3)1393

MDL号：MFCD00017777

PubChem编号：12070

别名：间溴苯甲酸甲酯

英文别名：METHYL 3-BROMOBENZOATE|618-89-3|3-Bromobenzoic Acid Methyl Ester|Methyl m-bromobenzoate|Benzoic acid, 3-bromo-, methyl ester|3-Bromobenzoic acid, methyl ester|Benzoic acid, m-bromo-, methyl ester|3-bromo-benzoic acid methyl ester|MFCD00017777|methyl-3-bro

规格或纯度：>99.0%(GC)

英文名称：Methyl 3-Bromobenzoate

运输条件：常规运输

产品介绍：Methyl 3-bromobenzoate is an aryl bromide. It undergoes stereoconvergent cross-coupling with potassium trifluoro(1-phenylethyl)borate to form 1,1-diarylethane derivative. The Negishi cross-coupling reaction between methyl 3-bromobenzoate and diarylzinc reagents in the presence of a palladium catalyst has been reported. Methyl-3-bromobenzoate can be converted into the corresponding benzonitrile using dichloro[bis{1-(dicyclohexylphosphanyl)piperidine}]palladium as a C-C cross-coupling catalyst and K4[Fe(CN)6] as a cyanating agent.Methyl 3-bromobenzoate is an aryl bromide. It undergoes stereoconvergent cross-coupling with potassium trifluoro(1-phenylethyl)borate to form 1,1-diarylethane derivative. The Negishi cross-coupling reaction between methyl 3-bromobenzoate and diarylzinc reagents in the presence of a palladium catalyst has been reported. Methyl-3-bromobenzoate can be converted into the corresponding benzonitrile using dichloro[bis{1-(dicyclohexylphosphanyl)piperidine}]palladium as a C-C cross-coupling catalyst and K4[Fe(CN)6] as a cyanating agent.

PubChem SID：488181530

PubChem SID url：https//pubchem.ncbi.nlm.nih.gov/substance/488181530

IUPAC Name：methyl 3-bromobenzoate

INCHI：InChI=1S/C8H7BrO2/c1-11-8(10)6-3-2-4-7(9)5-6/h2-5H,1H3

InChi Key：KMFJVYMFCAIRAN-UHFFFAOYSA-N

Canonical SMILES：COC(=O)C1=CC(=CC=C1)Br

Isomeric SMILES：COC(=O)C1=CC(=CC=C1)Br

WGK Germany：3

PubChem CID：12070

Reaxy-Rn：1940810

折光率：1.5575

闪点(℉)：230°F

闪点(℃)：>110°C

沸点：127-128°C/15 mmHg

熔点：31-33°C

象形图：

信号词：Warning

危险声明：H315 Causes skin irritationH319 Causes serious eye irritationH335 May cause respiratory irritationH302 Harmful if swallowedH312 Harmful in contact with skinH332 Harmful if inhaled

预防措施声明：P261,P305+P351+P338,P280,P302+P352,P321,P405,P501,P264,P271,P270,P304+P340,P403+P233,P362+P364,P330,P264+P265,P301+P317,P317,P337+P317,P332+P317,P319

个人防护装备：Eyeshields， Gloves， type N95 (US)， type P1 (EN143) respirator filter

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