产品名称

英文名称：1,5,7-Triazabicyclo[4.4.0]dec-5-ene

同义词

1,5,7-Triazabicyclo[4.4.0]dec-5-ene 、 3,4,6,7,8,9-hexahydro-2H-pyrimido[1,2-a]pyrimidine 、 1,3,4,6,7,8-Hexahydro-2H-pyrimido[1,2-a]pyrimidine 、 2,3,4,6,7,8-Hexahydro-1H-pyrimido[1,2-a]pyrimidine 、 1,3,4,6,7,8-Hexahydro-2H-pyrimido(1,2-a)pyrimidine 、 Triaz、1,3,4,6,7,8-六氢-2H-嘧啶并[1,2-a]嘧啶

产品性质

CAS编号：5807-14-7

分子式：C7H13N3

分子量：139.20

Beilstein号：3242

MDL号：MFCD00043003

PubChem编号：79873

别名：1,3,4,6,7,8-六氢-2H-嘧啶并[1,2-a]嘧啶

英文别名：1,5,7-Triazabicyclo[4.4.0]dec-5-ene | 3,4,6,7,8,9-hexahydro-2H-pyrimido[1,2-a]pyrimidine | 1,3,4,6,7,8-Hexahydro-2H-pyrimido[1,2-a]pyrimidine | 2,3,4,6,7,8-Hexahydro-1H-pyrimido[1,2-a]pyrimidine | 1,3,4,6,7,8-Hexahydro-2H-pyrimido(1,2-a)pyrimidine | Triaz

规格或纯度：98%

英文名称：1,5,7-Triazabicyclo[4.4.0]dec-5-ene

储存温度：充氩

运输条件：常规运输

产品介绍：1,5,7-三氮杂双环[4.4.0]癸-5-烯，一种双环胍碱，已被发现是迈克尔和迈克尔型反应的优良催化剂。它可与拉沙里菌素酸形成11复合物，并且其晶体结构已通过X射线衍射、FT-IR光谱和1H NMR进行研究。应用1,5,7-三氮杂双环[4.4.0]癸-5-烯可用作酯氨解过程的有机催化剂。它可以用作催化剂，用于在各种活化的烯烃中直接加入P（O）-H键（二烷基亚磷酸酯和二苯基亚膦酸酯）。聚合物负载的1,5,7-三氮杂双环[4.4.0]癸-5-烯（PTBD）可用作碱和试剂清除剂，以用于由酚和烷基或芳基卤化物合成芳基醚。 1,5,7-triazobicyclic [4.4.0]deca-5-ene, a bicyclic guanidine base, has been found to be an excellent catalyst for Michael Michael type reactions. It can form a 11 complex with Lasalitinic acid, and its crystal structure has been studied by X-ray diffraction, FT-IR spectroscopy, and 1H NMR.Application1,5,7-triazabicyclic [4.4.0]dec-5-ene can be used as an organic catalyst for ester ammonolysis. It can be used as a catalyst for directly adding P (O) - H bonds (dialkyl phosphites and diphenylphosphates) to various activated olefins. Polymer loaded 1,5,7-triazobicyclic [4.4.0]deca-5-ene (PTBD) can be used as a base and reagent scavenger for the synthesis of aryl ethers from phenols and alkyl or aryl halides.

IUPAC Name：3,4,6,7,8,9-hexahydro-2H-pyrimido[1,2-a]pyrimidine

INCHI：InChI=1S/C7H13N3/c1-3-8-7-9-4-2-6-10(7)5-1/h1-6H2,(H,8,9)

InChi Key：FVKFHMNJTHKMRX-UHFFFAOYSA-N

Canonical SMILES：C1CNC2=NCCCN2C1

Isomeric SMILES：C1CNC2=NCCCN2C1

WGK Germany：3

PubChem CID：79873

Reaxy-Rn：3242

敏感性：对湿度敏感；对空气敏感

熔点：130 °C

象形图：

信号词：Danger

危险声明：H314 Causes severe skin burns and eye damageH318 Causes serious eye damage

预防措施声明：P280,P321,P405,P501,P264,P260,P301+P330+P331,P304+P340,P363,P264+P265,P305+P354+P338,P317,P302+P361+P354,P316

个人防护装备：Eyeshields， Faceshields， full-face particle respirator type N100 (US)， Gloves， respirator cartridge type N100 (US)， type P1 (EN143) respirator filter， type P3 (EN 143) respirator cartridges

产品包装