产品名称

英文名称：Chloro(pentamethylcyclopentadienyl)(cyclooctadiene)ruthenium

同义词

Ru(cod)(C5Me5)Cl;Chloro(1,5-cyclooctadiene)pentamethylcyclopentadienylruthenium(II);1，5-Cyclooctadiene， ruthenium complex，Chloro(1，5-cyclooctadiene)(η5-pentamethylcyclopentadienyl)ruthenium，Chloro(1，5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium，、Ru(cod)(C5Me5)Cl;Chloro(1,5-cyclooctadiene)pentamethylcyclopentadienylruthenium(II);1，5-Cyclooctadiene， ruthenium complex，Chloro(1，5-cyclooctadiene)(η5-pentamethylcyclopentadienyl)ruthenium，Chloro(1，5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium，

产品性质

CAS编号：92390-26-6

分子式：C18H27ClRu

分子量：379.93

MDL号：MFCD07369035

别名：Ru(cod)(C5Me5)Cl;Chloro(1,5-cyclooctadiene)pentamethylcyclopentadienylruthenium(II);1，5-Cyclooctadiene， ruthenium complex，Chloro(1，5-cyclooctadiene)(η5-pentamethylcyclopentadienyl)ruthenium，Chloro(1，5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium，

英文别名：Ru(cod)(C5Me5)Cl;Chloro(1,5-cyclooctadiene)pentamethylcyclopentadienylruthenium(II);1，5-Cyclooctadiene， ruthenium complex，Chloro(1，5-cyclooctadiene)(η5-pentamethylcyclopentadienyl)ruthenium，Chloro(1，5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium，

规格或纯度：96%

英文名称：Chloro(pentamethylcyclopentadienyl)(cyclooctadiene)ruthenium

储存温度：-20°C储存,充氩

运输条件：超低温冰袋运输

备注：1g卖完停产，不再备货

产品介绍：应用(1,5-环辛二烯)(五甲基环戊二烯)氯化钌是用于形成碳-碳和碳-杂原子键的均相催化剂。它可用于催化炔基硼酸酯、炔丙醇和末端炔烃的环化三聚反应(cyclotrimerization)以形成芳基硼酸酯，芳基硼酸酯可进行钯（II）催化的羰基化反应以形成高度取代的苯酞。催化降冰片烯和降冰片二烯与炔烃的C-C偶联以形成2 + 2环加成产物。与2-二苯基膦基乙胺-叔丁醇钾结合形成一种可催化手性非外消旋仲醇快速消旋的三元催化剂体系。合成具有磷基配体（如双膦胺）的新有机钌配合物催化有机二硫化物和烯烃的加成反应生成二甲基二硫醚（vic-dithioether）。Product classM-C, Homogeneous Catalysts, Arene/Aryl Ligands, Diene/Dienyl LigandsReaction typeCyclization, Cyclopropanation, Ring Opening ReactionChemical propertiesChemical formulaC18H27ClRuEmpirical formulaRu(cod)(C5Me5)ClMolecular weight379.93MetalRuTheoretical metal content27Physical statecrystallineColorbrown orange

INCHI：1S/C10H15.C8H12.ClH.Ru/c1-6-7(2)9(4)10(5)8(6)3;1-2-4-6-8-7-5-3-1;;/h1-5H3;1-2,7-8H,3-6H2;1H;/q;;;+1/p-1/b;2-1-,8-7-;;

InChi Key：MQMQNIQJGNBEMG-ONEVTFJLSA-M

Canonical SMILES：[Ru]Cl.C[C]1[C](C)[C](C)[C](C)[C]1C.C1C=CCCC=CC1;CC1C(C)C(C)C(C)C1C.C[Ru](C)(C)Cl.C1C=CCCC=CC1

WGK Germany：3

UN Number：3395

Packing Group：II

熔点：143-147°C

象形图：

信号词：Danger

危险声明：H261 In contact with water releases flammable gas

预防措施声明：P231+P232,P422

Class：4.3

个人防护装备：Eyeshields, Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges

产品包装