产品名称

英文名称：6,6-Dimethylfulvene

同义词

6,6-Dimethylfulvene、2175-91-9、5-(propan-2-ylidene)cyclopenta-1,3-diene、5-propan-2-ylidenecyclopenta-1,3-diene、1,3-Cyclopentadiene, 5-(1-methylethylidene)-、Dimethylfulvene、5-Isopropylidene-1,3-cyclopentadiene、6,6'-Dimethylfulvene、Isopropylidenecyclopentadi、6,6-二甲基富烯、5-(1-甲基亚乙基)-1,3-环戊二烯, 5-异亚丙基-1,3-环戊二烯、5-(二甲基亚甲基)-1,3-环戊二烯

产品性质

CAS编号：2175-91-9

分子式：C8H10

分子量：106.17

MDL号：MFCD00011655

PubChem编号：137467

别名：6,6-二甲基富烯|5-(1-甲基亚乙基)-1,3-环戊二烯, 5-异亚丙基-1,3-环戊二烯|5-(二甲基亚甲基)-1,3-环戊二烯

英文别名：6,6-Dimethylfulvene|2175-91-9|5-(propan-2-ylidene)cyclopenta-1,3-diene|5-propan-2-ylidenecyclopenta-1,3-diene|1,3-Cyclopentadiene, 5-(1-methylethylidene)-|Dimethylfulvene|5-Isopropylidene-1,3-cyclopentadiene|6,6'-Dimethylfulvene|Isopropylidenecyclopentadi

规格或纯度：95%

英文名称：6,6-Dimethylfulvene

储存温度：-20°C储存,充氩

运输条件：超低温冰袋运输

产品介绍：6,6-Dimethylfulvene [5-(1-methylethylidene)-1,3-cyclopentadiene] is a nonaromatic carbocyclic analog of isopropylbenzene.6,6-Dimethylfulvene reacts with 2,2-bis(trifluoromethyl)-1,1-dicyanoethylene (BTF; 1) to afford the expected Diels-Alder cycloadduct, 7-(1-methylethylidene)-3,3-bis(trifluoromethyl)bicyclo[2.2.1]hept-5-ene-2,2-dicarbonitrile.Metal-free hydrogenation of 6,6-dimethylfulvene via frustrated Lewis pair (FLP) mediated triple domino reaction has been reported.The biotransformation of 6,6-dimethylfulvene by Pseudomonas putida RE213 has been studied.Cycloaddition of 6,6-dimethylfulvene with benzynes has been reported. 6,6-Dimethylfulvene may be employed in the following studies · One-pot synthesis of ansa-metallocenes. · Synthesis of endo and exo-adducts with maleic anhydride. · Synthesis of fulvenols or the corresponding trimethylsilyl ethers6,6-Dimethylfulvene [5-(1-methylethylidene)-1,3-cyclopentadiene] is a nonaromatic carbocyclic analog of isopropylbenzene.6,6-Dimethylfulvene reacts with 2,2-bis(trifluoromethyl)-1,1-dicyanoethylene (BTF; 1) to afford the expected Diels-Alder cycloadduct, 7-(1-methylethylidene)-3,3-bis(trifluoromethyl)bicyclo[2.2.1]hept-5-ene-2,2-dicarbonitrile.Metal-free hydrogenation of 6,6-dimethylfulvene via frustrated Lewis pair (FLP) mediated triple domino reaction has been reported.The biotransformation of 6,6-dimethylfulvene by Pseudomonas putida RE213 has been studied.Cycloaddition of 6,6-dimethylfulvene with benzynes has been reported.

IUPAC Name：5-propan-2-ylidenecyclopenta-1,3-diene

INCHI：InChI=1S/C8H10/c1-7(2)8-5-3-4-6-8/h3-6H,1-2H3

InChi Key：WXACXMWYHXOSIX-UHFFFAOYSA-N

Canonical SMILES：CC(=C1C=CC=C1)C

Isomeric SMILES：CC(=C1C=CC=C1)C

WGK Germany：3

PubChem CID：137467

Reaxy-Rn：1616308

密度：0.881

敏感性：对空气敏感;对热敏感

折光率：1.548

闪点(℉)：109.4 °F

闪点(℃)：43 °C

沸点：76-77 °C/50 mmHg

熔点：3°C

象形图：

信号词：Danger

危险声明：H226 Flammable liquid and vaporH304 May be fatal if swallowed and enters airways

预防措施声明：P280,P370+P378,P210,P405,P501,P233,P240,P403+P235,P303+P361+P353,P241,P331,P242,P243,P301+P316

个人防护装备：Eyeshields， Faceshields， full-face respirator (US)， Gloves， multi-purpose combination respirator cartridge (US)， type ABEK (EN14387) respirator filter

产品包装