产品名称

英文名称：(R,R)-(-)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine

同义词

135616-40-9、(R,R)-(-)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine、(1R,2R)-1,2-Bis[[[3,5-bis(tert-butyl)-2-hydroxyphenyl]methylene]amino]cyclohexane、MFCD00191800、(R,R)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine、(R,R)-、(R,R)-雅可布逊配体、(R,R)-Jacobsen 配体

产品性质

CAS编号：135616-40-9

分子式：[[(CH3)3C]2C6H2-2-(OH)CH=N]2C6H10

分子量：546.83

Beilstein号：5464823

MDL号：MFCD00191800

PubChem编号：2733339

别名：(R,R)-雅可布逊配体|(R,R)-Jacobsen 配体

英文别名：135616-40-9|(R,R)-(-)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine|(1R,2R)-1,2-Bis[[[3,5-bis(tert-butyl)-2-hydroxyphenyl]methylene]amino]cyclohexane|MFCD00191800|(R,R)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine|(R,R)-

规格或纯度：96%

英文名称：(R,R)-(-)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine

生化机理：Lipases catalyze the hydrolysis of triacylglycerols into glycerol and free fatty acids. α-amylase catalyzes the hydrolysis of internal α-1,4-O-glycosidic bonds in starches to release α-anomeric sμgars.

应用：配体，参与非对称催化反应。用于制备Jacobsen催化剂，应用于缺失功能基团烯烃的对映选择性环氧化反应。(R,R)-(−)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine

运输条件：常规运输

产品介绍：溶于水。 配体，参与非对称催化反应。用于制备Jacobsen催化剂，应用于缺失功能基团烯烃的对映选择性环氧化反应。(R,R)-(−)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine

PubChem SID：488192388

IUPAC Name：2,4-ditert-butyl-6-[[(1R,2R)-2-[(3,5-ditert-butyl-2-hydroxyphenyl)methylideneamino]cyclohexyl]iminomethyl]phenol

INCHI：InChI=1S/C36H54N2O2/c1-33(2,3)25-17-23(31(39)27(19-25)35(7,8)9)21-37-29-15-13-14-16-30(29)38-22-24-18-26(34(4,5)6)20-28(32(24)40)36(10,11)12/h17-22,29-30,39-40H,13-16H2,1-12H3/t29-,30-/m1/s1

InChi Key：FYNXDGNCEBQLGC-LOYHVIPDSA-N

Canonical SMILES：CC(C)(C)C1=CC(=C(C(=C1)C(C)(C)C)O)C=NC2CCCCC2N=CC3=C(C(=CC(=C3)C(C)(C)C)C(C)(C)C)O

Isomeric SMILES：CC(C)(C)C1=CC(=C(C(=C1)C(C)(C)C)O)C=N[C@@H]2CCCC[C@H]2N=CC3=C(C(=CC(=C3)C(C)(C)C)C(C)(C)C)O

WGK Germany：3

PubChem CID：2733339

溶解性：可溶于甲苯

比旋光度：-321° (C=1,CH2Cl2)

熔点：205-207°C

象形图：

信号词：Warning

危险声明：H315 Causes skin irritationH319 Causes serious eye irritationH335 May cause respiratory irritation

预防措施声明：P261,P305+P351+P338,P280,P302+P352,P321,P405,P501,P264,P271,P304+P340,P403+P233,P362+P364,P264+P265,P337+P317,P332+P317,P319

个人防护装备：dust mask type N95 (US),Eyeshields,Gloves

产品包装