产品名称

英文名称：(Acetylacetonato)(1,5-cyclooctadiene)rhodium(I)

同义词

Rh(acac)(COD)、Acetylacetonato(1,5-cyclooctadiene)rhodium(I)、(1Z,5Z)-cycloocta-1,5-diene;(Z)-4-hydroxypent-3-en-2-one;rhodium、(Acetylacetonato)(1,5-cyclooctadiene)rhodium(I)、(Acetylacetonato)(1,5-cyclooctadiene)rhodium(I), 99%、AKOS025117565、AKOS037646062、A

产品性质

CAS编号：12245-39-5

分子式：C13H19O2Rh

分子量：310.19

MDL号：MFCD00075046

PubChem编号：10935795

英文别名：Rh(acac)(COD)|Acetylacetonato(1,5-cyclooctadiene)rhodium(I)|(1Z,5Z)-cycloocta-1,5-diene;(Z)-4-hydroxypent-3-en-2-one;rhodium|(Acetylacetonato)(1,5-cyclooctadiene)rhodium(I)|(Acetylacetonato)(1,5-cyclooctadiene)rhodium(I), 99%|AKOS025117565|AKOS037646062|A

规格或纯度：99%

英文名称：(Acetylacetonato)(1,5-cyclooctadiene)rhodium(I)

法律信息：Product of Umicore

储存温度：室温

运输条件：常规运输

产品介绍：ApplicationCatalyst/precursor for enantioselective/asymmetric hydrogenations, isomerization/hydroformylations, carbozincation reactions, and silylation of aryl electrophilesProduct classM-O, Homogeneous Catalysts, M-C, Diene/Dienyl Ligands, Acetylacetonate LigandsReaction typeHydrogenation, Asymmetric Reactions, CH-Activation, Hydroformylation, Asymmetric Hydrogenation, IsomerizationChemical propertiesChemical formulaC13H19O2RhEmpirical formulaRh(cod)(acac)Molecular weight310.20MetalRhTheoretical metal content33Physical statecrystallineColoryellowApplicationCatalyst/precursor for enantioselective/asymmetric hydrogenations, isomerization/hydroformylations, carbozincation reactions, and silylation of aryl electrophilesProduct classM-O, Homogeneous Catalysts, M-C, Diene/Dienyl Ligands, Acetylacetonate LigandsReaction typeHydrogenation, Asymmetric Reactions, CH-Activation, Hydroformylation, Asymmetric Hydrogenation, IsomerizationChemical propertiesChemical formulaC13H19O2RhEmpirical formulaRh(cod)(acac)Molecular weight310.20MetalRhTheoretical metal content33Physical statecrystallineColoryellow

IUPAC Name：(1Z,5Z)-cycloocta-1,5-diene;(Z)-4-hydroxypent-3-en-2-one;rhodium

INCHI：InChI=1S/C8H12.C5H8O2.Rh/c1-2-4-6-8-7-5-3-1;1-4(6)3-5(2)7;/h1-2,7-8H,3-6H2;3,6H,1-2H3;/b2-1-,8-7-;4-3-;

InChi Key：BUYVJWVYKPKZEX-DWVXZKBMSA-N

Canonical SMILES：CC(=CC(=O)C)O.C1CC=CCCC=C1.[Rh]

Isomeric SMILES：C/C(=C/C(=O)C)/O.C1/C=C\CC/C=C\C1.[Rh]

WGK Germany：3

RTECS：VI9292000

PubChem CID：10935795

PubChem SID：488196947

敏感性：对空气敏感

熔点：138-140 °C (lit.)

象形图：

信号词：Warning

危险声明：H315 Causes skin irritationH319 Causes serious eye irritation

预防措施声明：P261,P305+P351+P338,P280,P302+P352,P321,P405,P501,P264,P271,P304+P340,P403+P233,P362+P364,P264+P265,P337+P317,P332+P317,P319

个人防护装备：dust mask type N95 (US),Eyeshields,Gloves

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