产品名称

英文名称：Allyl[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]chloropalladium(II)

同义词

烯丙基[1,3-双(2,6-二异丙基苯基)咪唑-2-亚基]氯化钯(II)

产品性质

CAS编号：478980-03-9

分子式：C30H41N2ClPd

分子量：571.53

MDL号：MFCD08561131

PubChem编号：254777602

别名：烯丙基[1,3-双(2,6-二异丙基苯基)咪唑-2-亚基]氯化钯(II)

规格或纯度：98%

英文名称：Allyl[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]chloropalladium(II)

储存温度：2-8°C储存,避光,充氩

运输条件：冰袋运输

产品介绍：Catalyst for the arylation of ketones, Suzuki coupling reaction, Buchwald-Hartwig amination reaction, dehalogenation of aryl chlorides, and oxidation of secondary alcohols.Allyl[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]chloropalladium(II) is an air-stable, well-defined palladium N-heterocyclic carbene complex, which can efficiently catalyze α-arylation of ketones.Catalyst for the arylation of ketones, Suzuki coupling reaction, Buchwald-Hartwig amination reaction, dehalogenation of aryl chlorides, and oxidation of secondary alcohols.Product classM-P, Homogeneous Catalysts, N-Heterocyclic Carbene Ligands, M-C, Allyl Ligands, IPr, Bidentate LigandsReaction typeCross Coupling Reactions with Arenes, Amination, Buchwald-Hartwig Aminaton, Alpha Arylation, Dehalogenation, Kumada Coupling Reaction, Mizoroki Heck Coupling Reaction, Oxidation, Suzuki-Miyaura Coupling Reaction, Dehalogenation, Oxidation, TelomerizationChemical propertiesChemical formulaC30H41N2ClPdEmpirical formula[(IPr)Pd(allyl)CI]Molecular weight571.54MetalPdTheoretical metal content19Physical statecrystallineApplications & referencesPalladium catalyzed anaerobic oxidation of secondary alcohols under mild reaction conditions.Reference J. Org. Chem. 2011, 76, 1390. (DOI 10.1021/jo102385u)One-pot oxidation / α-ketone arylation of secondary alcohols.Reference J. Org. Chem. 2011, 76, 1390. (DOI 10.1021/jo102385u)Palladium catalyzed Buchwald-Hartwig-Reaction at room temperature.Reference J. Am. Chem. Soc. 2006, 128, 4101. (DOI 10.10217ja057704z)α-Arylation of propiophenone.Reference Org. Lett. 2002, 4, 4053 (DOI 10.1021/ol026745m)Intramolecular arylamination step in the total synthesis of cryptocarya alkaloids.Reference Synlett 2003, 12, 1871 (DOI 10.1055/s-2003-41468)Dehalogenation reaction.Reference J. Org. Chem. 2004, 69, 3173 (DOI 10.1021/jo035834p)Suzuki-Miyaura coupling reaction.Reference J. Am. Chem. Soc. 2006, 128, 4101. (DOI 10.10217ja057704z)

INCHI：1S/C27H37N2.C3H5.ClH.Pd/c1-18(2)22-11-9-12-23(19(3)4)26(22)28-15-16-29(17-28)27-24(20(5)6)13-10-14-25(27)21(7)8;1-3-2;;/h9-21H,1-8H3;3H,1-2H2;1H;/q;;;+1/p-1

InChi Key：YVIDBHQABBIAAW-UHFFFAOYSA-M

Canonical SMILES：[CH2][CH][CH2].CC(C)c1cccc(C(C)C)c1N2C=CN(C2[Pd]Cl)c3c(cccc3C(C)C)C(C)C

WGK Germany：3

PubChem CID：254777602

敏感性：对光线敏感

熔点：>300°C

象形图：

信号词：Warning

危险声明：H315 Causes skin irritationH319 Causes serious eye irritationH335 May cause respiratory irritation

预防措施声明：P261,P305+P351+P338,P302+P352

个人防护装备：dust mask type N95 (US), Eyeshields, Gloves

产品包装