产品名称

英文名称：(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a;3,4-a']dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine.

同义词

(S,S,S)-(+)-(3,5-二氧杂-4-磷杂环庚二烯并[2,1-a3,4-a']二萘-4-基)二(1-苯基乙基)胺

产品性质

CAS编号：380230-02-4

分子式：C36H30NO2P

分子量：539.6

MDL号：MFCD04117688

PubChem编号：11731247

别名：(S,S,S)-(+)-(3,5-二氧杂-4-磷杂环庚二烯并[2,1-a3,4-a']二萘-4-基)二(1-苯基乙基)胺

规格或纯度：≥97%

英文名称：(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a;3,4-a']dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine.

储存温度：充氩

运输条件：常规运输

备注：卖完停产，不再备货

产品介绍：手性亚磷酰胺配体，用于铜催化的高对映选择性共轭加成反应，该反应可将二烷基锌加成到各种 Michael 受体。也可用于二乙基锌介导的钯催化极性反转烯丙基化反应。The product may be used as a ligand in . Iridium-catalyzed allylic etherification of acyclic, achiral allylic carbonates with potassium silanolates to form chiral allylic alcohols. . Palladium-catalyzed asymmetric allylic cyclisation of N-tosyl and N-benzyl carbonates to form the corresponding pyrrolidine and piperidine derivatives, respectively. . Intramolecular iridium-catalyzed allylic cyclizationof (E)-allylic methyl carbonates to form 2,5-trans/cis pyrrolidine derivatives.

IUPAC Name：N,N-bis[(1S)-1-phenylethyl]-12,14-dioxa-13-phosphapentacyclo[13.8.0.02,11.03,8.018,23]tricosa-1(15),2(11),3,5,7,9,16,18,20,22-decaen-13-amine

INCHI：InChI=1S/C36H30NO2P/c1-25(27-13-5-3-6-14-27)37(26(2)28-15-7-4-8-16-28)40-38-33-23-21-29-17-9-11-19-31(29)35(33)36-32-20-12-10-18-30(32)22-24-34(36)39-40/h3-26H,1-2H3/t25-,26-/m0/s1

InChi Key：LKZPDRCMCSBQFN-UIOOFZCWSA-N

Canonical SMILES：CC(C1=CC=CC=C1)N(C(C)C2=CC=CC=C2)P3OC4=C(C5=CC=CC=C5C=C4)C6=C(O3)C=CC7=CC=CC=C76

Isomeric SMILES：C[C@@H](C1=CC=CC=C1)N([C@@H](C)C2=CC=CC=C2)P3OC4=C(C5=CC=CC=C5C=C4)C6=C(O3)C=CC7=CC=CC=C76

WGK Germany：3

PubChem CID：11731247

敏感性：对湿度敏感.

个人防护装备：Eyeshields， Gloves， type N95 (US)， type P1 (EN143) respirator filter

产品包装