产品名称

英文名称：(S)-(-)-α-Methylbenzyl Isocyanate

同义词

14649-03-7、(S)-(-)-1-Phenylethyl isocyanate、[(1S)-1-isocyanatoethyl]benzene、(S)-(-)-alpha-Methylbenzyl isocyanate、(S)-(-)-1-Phenylethylisocyanate、(S)-1-PHENYLETHYLISOCYANATE、MFCD00002036、Benzene, [(1S)-1-isocyanatoethyl]-、(1-Isocyanatoethyl)benzene #、(S)-、(S)-(-)-1-苯乙基异氰酸酯

产品性质

CAS编号：14649-03-7

分子式：C9H9NO

分子量：147.18

MDL号：MFCD00002036

PubChem编号：2724173

别名：(S)-(-)-1-苯乙基异氰酸酯

英文别名：14649-03-7|(S)-(-)-1-Phenylethyl isocyanate|[(1S)-1-isocyanatoethyl]benzene|(S)-(-)-alpha-Methylbenzyl isocyanate|(S)-(-)-1-Phenylethylisocyanate|(S)-1-PHENYLETHYLISOCYANATE|MFCD00002036|Benzene, [(1S)-1-isocyanatoethyl]-|(1-Isocyanatoethyl)benzene #|(S)-

规格或纯度：99%

英文名称：(S)-(-)-α-Methylbenzyl Isocyanate

应用：(S)-(-)-α-甲基苄基异氰酸酯可作为拆分外消旋 (±)-6aR,11aR-高丽槐素的手性辅助剂，得到 (-)-形式，这是合成 (-)-卡本格林 A-I 的关键中间体。

储存温度：2-8°C储存,充氩

运输条件：冰袋运输

产品介绍：(S)-(-)-α-甲基苄基异氰酸酯是拆分对映体常用的手性衍生剂。(S)-(-)-α-甲基苄基异氰酸酯可作为拆分外消旋 (±)-6aR,11aR-高丽槐素的手性辅助剂，得到 (-)-形式，这是合成 (-)-卡本格林 A-I 的关键中间体。(S)-(-)-α-Methylbenzyl isocyanate is a commonly used chiral derivatizing agent for the resolution of enantiomers.(S)-(-)-α-Methylbenzyl isocyanate may be used as a chiral auxiliary for the resolution of racemic (±)-6aR,11aR-maackiain to give the (-)-form, which is a key intermediate for synthesizing (-)-cabenegrin A-I.

IUPAC Name：[(1S)-1-isocyanatoethyl]benzene

INCHI：InChI=1S/C9H9NO/c1-8(10-7-11)9-5-3-2-4-6-9/h2-6,8H,1H3/t8-/m0/s1

InChi Key：JJSCUXAFAJEQGB-QMMMGPOBSA-N

Canonical SMILES：CC(C1=CC=CC=C1)N=C=O

Isomeric SMILES：C[C@@H](C1=CC=CC=C1)N=C=O

PubChem CID：2724173

溶解性：Solubility in water decomposes

密度：1.05

敏感性：对热、湿度敏感

折光率：1.51

比旋光度：-10° (neat)

闪点(℉)：149 °F

闪点(℃)：65 °C

沸点：98 °C/23 mmHg

象形图：

信号词：Danger

危险声明：H315 Causes skin irritationH319 Causes serious eye irritationH335 May cause respiratory irritationH331 Toxic if inhaledH302 Harmful if swallowedH334 May cause allergy or asthma symptoms or breathing difficulties if inhaledH330 Fatal if inhaled

预防措施声明：P261,P305+P351+P338,P280,P302+P352,P321,P405,P501,P264,P260,P284,P271,P270,P304+P340,P403+P233,P362+P364,P330,P320,P264+P265,P301+P317,P337+P317,P332+P317,P316,P319,P342+P316

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