产品名称

英文名称：Trimethylsulfoxonium Iodide

同义词

Trimethylsulfoxonium iodide、1774-47-6、Trimethylsulphoxonium iodide、Trimethyloxosulfonium iodide、Sulfoxonium, trimethyl-, iodide、Trimethyloxosulphonium iodide、Sulfoxonium, trimethyl-, iodide (11)、MFCD00011899、Trimethylsulfoxoniumiodide、Trimethyl sulphoxon、三甲基硫氧碘代物

产品性质

CAS编号：1774-47-6

分子式：C3H9IOS

分子量：220.07

MDL号：MFCD00011899

PubChem编号：74498

别名：三甲基硫氧碘代物

英文别名：Trimethylsulfoxonium iodide|1774-47-6|Trimethylsulphoxonium iodide|Trimethyloxosulfonium iodide|Sulfoxonium, trimethyl-, iodide|Trimethyloxosulphonium iodide|Sulfoxonium, trimethyl-, iodide (11)|MFCD00011899|Trimethylsulfoxoniumiodide|Trimethyl sulphoxon

规格或纯度：>98.0%(T)

英文名称：Trimethylsulfoxonium Iodide

应用：用强碱处理可生成内鎓盐，内鎓盐可与酮和醛的羰基发生加成反应生成环氧化物。也可优先与 α,β-不饱和酯的双键发生加成反应生成环丙酯。

运输条件：常规运输

产品介绍：用强碱处理可生成内鎓盐，内鎓盐可与酮和醛的羰基发生加成反应生成环氧化物。也可优先与 α,β-不饱和酯的双键发生加成反应生成环丙酯。Treatment with strong base yields the ylide which adds to the carbonyl group of ketones and aldehydes to give epoxides. Also adds preferentially to the double bond of α,β-unsaturated esters to give cyclopropyl esters.

INCHI：InChI=1S/C3H9OS.HI/c1-5(2,3)4;/h1-3H3;1H/q+1;/p-1

InChi Key：BPLKQGGAXWRFOE-UHFFFAOYSA-M

Canonical SMILES：C[S+](=O)(C)C.[I-]

Isomeric SMILES：C[S+](=O)(C)C.[I-]

PubChem CID：74498

溶解性：Soluble in water.

敏感性：对光线敏感

熔点：170°C

象形图：

信号词：Warning

危险声明：H315 Causes skin irritationH319 Causes serious eye irritationH335 May cause respiratory irritationH411 Toxic to aquatic life with long lasting effectsH303 May be harmful if swallowedH401 Toxic to aquatic lifeH320 Causes eye irritation

预防措施声明：P261,P305+P351+P338,P273,P280,P302+P352,P321,P405,P501,P264,P271,P304+P340,P403+P233,P362+P364,P391,P264+P265,P301+P317,P337+P317,P332+P317,P319

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