产品名称

英文名称：Phenylboronic acid (contains varying amounts of Anhydride)

同义词

Phenyldihydroxyborane 、 Borophenylic acid 、 Dihydroxy(phenyl)borane 、 Phenylboronic acid 、 Benzeneboronic acid 、 Dihydroxyphenylborane 、 USAF BO-2、二羟基苯硼烷 、 苯基硼酸

产品性质

CAS编号：98-80-6

分子式：C6H7BO2

分子量：121.93

Beilstein号：970972

EC号：202-701-9

MDL号：MFCD00002103

PubChem编号：66827

别名：二羟基苯硼烷 | 苯基硼酸

英文别名：Phenyldihydroxyborane | Borophenylic acid | Dihydroxy(phenyl)borane | Phenylboronic acid | Benzeneboronic acid | Dihydroxyphenylborane | USAF BO-2

规格或纯度：97%

英文名称：Phenylboronic acid (contains varying amounts of Anhydride)

储存温度：充氩

运输条件：常规运输

备注：5g/10g/50g/500g卖完停产，不再备货

产品介绍：溶于甲醇和乙醇,难溶于水和乙醚。 溶解度分别为10 g/L水 (20°C)，溶于 1.75%苯 、1.2 %二甲苯、 178 %甲醇和30.2%乙醚 Phenylboronic acid may be employed in the following reactions Rhodium-catalyzed intramolecular amination. Pd-catalyzed direct arylation. Mizoroki-Heck and Suzuki-Miyaura coupling reactions catalyzed by palladium nanoparticles. Palladium-catalyzed stereoselective Heck-type reaction. Highly effective Palladium-catalyzed arylation Suzuki-Miyaura cross-coupling in water. Phenylboronic acid may be employed as reagent in the preparation of Ni(II) pincer complex and Pd(II) pyridoxal hydrazone metallacycles as catalysts for the Suzuki-Miyaura cross-coupling reactions. N-type polymers for all-polymer solar cells. Novel series of potent and selective mTOR kinase inhibitors. Inhibitors of lactate dehydrogenase against cancer cell proliferation.Contains varying amounts of phenylboronic anhydride.Microwave-assisted Suzuki coupling of aryl chlorides with phenylboronic acid in the presence of Pd/C (catalyst) and water (solvent) has been described.Palladium-catalyzed cross-coupling reaction of phenylboronicacid with haloarenes to afford biaryls has been reported.Phenylboronic acid may be employed in the following reactions Rhodium-catalyzed intramolecular amination. Pd-catalyzed direct arylation. Mizoroki-Heck and Suzuki-Miyaura coupling reactions catalyzed by palladium nanoparticles. Palladium-catalyzed stereoselective Heck-type reaction. Highly effective Palladium-catalyzed arylation Suzuki-Miyaura cross-coupling in water. Phenylboronic acid may be employed as reagent in the preparation of Ni(II) pincer complex and Pd(II) pyridoxal hydrazone metallacycles as catalysts for the Suzuki-Miyaura cross-coupling reactions. N-type polymers for all-polymer solar cells. Novel series of potent and selective mTOR kinase inhibitors. Inhibitors of lactate dehydrogenase against cancer cell proliferation.

IUPAC Name：phenylboronic acid

INCHI：InChI=1S/C6H7BO2/c8-7(9)6-4-2-1-3-5-6/h1-5,8-9H

InChi Key：HXITXNWTGFUOAU-UHFFFAOYSA-N

Canonical SMILES：B(C1=CC=CC=C1)(O)O

Isomeric SMILES：B(C1=CC=CC=C1)(O)O

WGK Germany：3

RTECS：CY8575000

PubChem CID：66827

Reaxy-Rn：970972

溶解性：Soluble in water (10 mg/ml at 20 °C), ether (30.2%), chloroform, methanol (178%), and DMSO.

密度：1.13

敏感性：易吸潮

熔点：217-220°C

象形图：

信号词：Warning

危险声明：H315 Causes skin irritationH319 Causes serious eye irritationH335 May cause respiratory irritationH302 Harmful if swallowed

预防措施声明：P261,P305+P351+P338,P280,P302+P352,P321,P405,P501,P264,P271,P270,P304+P340,P403+P233,P362+P364,P330,P264+P265,P301+P317,P337+P317,P332+P317,P319

Merck Index：1068

个人防护装备：dust mask type N95 (US),Eyeshields,Gloves

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